The annotated papers that are submitted as part of this thesis consider the phenomenon of colour at the fundamental, technical, and application levels, and they were written and published by Oulton between 1990 and 2009. The papers disclose significant insights by the author into colorimetric modeling theory and report aspects of the author's work that have led to commercially successful practical applications. The academic significance of these papers is evident in their citation record; their practical value is shown by a number of successful industrial collaboration programmes, and through the award of national prizes for innovation by the Worshipful Company of Dyers, and the Society of Dyers and Colorists. The published research primarily concerns digital devices that either capture or reproduce coloured images. For example, the research problem of how to calibrate the colour on computer CRT screens, which was thought at the time to be intractable, was reported by Oulton in paper 1 to be solved at the two to three significant figure level of colorimetric accuracy. This world leading level of accuracy was subsequently confirmed using a comprehensive data set in paper 7, and has been exploited internationally in commercial computer aided design and colour communication systems by Textile Computer Systems Ltd and Datacolor Inc. Further research problems resolved by Oulton in the presented papers include how to predict the colorimetric sensitivity of dye recipes; how to design, test, and fine-tune the spectral response of digital cameras; and how the individual customers in a shop can be tracked automatically to reveal their buying behavior, using coloured CCTV images.The challenge to the standard CIE colorimetric model posed by the results of Dr W.A.Thornton was analyzed and satisfactorily explained by Oulton in papers 2, 3 and 4. It is also shown that Thornton's results do not in any way compromise either the practice of colorimetry based on the CIE Standard Observer, or the validity of its quantifying data sets. It is also additionally shown under the annotation of paper 4 presented here, that the success of the CIE colorimetric model has a clearly demonstrable theoretical basis.In all but one of the presented papers the convention is maintained that the standard CIE XYZ co-ordinate model should be used as the reference basis, when modeling the properties of colour and quantifying its uses. The final paper to be published (and presented here as paper 4) challenges this convention and demonstrates that a context free and formally defined alternative reference basis may be used in colorimetric modeling with significant advantage.It is also shown in paper 4 that under the specified axioms, any cross dependency that is potentially non linear can in principle be resolved into its component scalar and additive relationships, and that the causes of scalar non linearity may be characterized independently from the causes of linearly additive cross dependency. The result is a widely applicable analytical and experimental design method for resolving complex cross dependent relationships in general and in particular, for resolving those between the spectral visual stimuli and the psychophysical response to them.