This PhD thesis, submitted to The University of Manchester, mainly refers to any fundamental knowledge of transport measurement, the description of different measurement instruments and my research based on transport measurement ranging from the single alignment between graphene and one side hBN to double alignment where graphene is intentionally aligned to hBN on both sides, and extended from graphene - hBN superlattice to other twisted heterostructures. Twisted superconductors NbSe2 has been discussed. Furthermore, the high-quality CVD graphene and exploration of twisted CVD graphene are also referred.