A study of Particle Structure and Film Formation Mechanism on the Mechanical Properties of Synthetic Rubber Films

UoM administered thesis: Phd

  • Authors:
  • Somjit Tungchaiwattana


This thesis investigated a new group of poly(Bd)/poly(Bd-co-MAA) core-shell particles that were ionically crosslinked and cast as nanostructured ionomer films from aqueous dispersions. The new group of poly(Bd)/poly(Bd-co-MAA) core-shell particles were studied for structure-property relationships and morphology. The covalent crosslinking content in the core and the shell were varied at constant ionic crosslinking. Stress-strain data showed control of the nanostructured films. The chain transfer agent used during the preparation of the nanoparticles core-shells was shown to independently tune the mechanical properties of the films.


Original languageEnglish
Awarding Institution
Award date31 Dec 2014