Prof Stephen Liddle

Professor & Head of Inorganic Chemistry

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Publications

  1. 2019
  2. Accepted/In press

    Preparation of Heterobimetallic Ketimido-Actinide-Molybdenum Complexes

    Ayres, A. J., Wooles, A., Zegke, M., Tuna, F. & Liddle, S., 5 Sep 2019, (Accepted/In press) In : Inorganic Chemistry.

    Research output: Contribution to journalArticle

  3. Published

    Back-bonding between an electron-poor, high-oxidation-state metal and poor π-acceptor ligand in a uranium(V)–dinitrogen complex

    Lu, E., Atkinson, B., Wooles, A., Boronski, J., Doyle, L., Tuna, F., Cryer, J., Cobb, P., Vitorica-Yrezabal, I., Whitehead, G., Kaltsoyannis, N. & Liddle, S., 19 Aug 2019, In : Nature Chemistry.

    Research output: Contribution to journalArticle

  4. Published

    Bimetallic Cooperative Cleavage of Dinitrogen to Nitride and Tandem Frustrated Lewis Pair Hydrogenation to Ammonia

    Liddle, S., Doyle, L. & Wooles, A., 2019, In : Angewandte Chemie International Edition.

    Research output: Contribution to journalArticle

  5. Published

    Emergence of the Structure-Directing Role of f-Orbital Overlap-Driven Covalency

    Lu, E., Sajjad, S., Berryman, V., Wooles, A., Kaltsoyannis, N. & Liddle, S., 2019, In : Nature Communications. 10, 634.

    Research output: Contribution to journalArticle

  6. Published

    Photolytic and Reductive Activations of 2‐Arsaethynolate in a Uranium‐Triamidoamine Complex: Decarbonylative Arsenic Group‐Transfer Reactions and Trapping of a Highly Bent and Reduced Form

    Liddle, S., Magnall, R., Balazs, G., Lu, E., Kern, M., Van Slageren, J., Tuna, F., Wooles, A. & Scheer, M., 2019, In : Chemistry – A European Journal.

    Research output: Contribution to journalArticle

  7. Published
  8. Published

    Studies of Hysteresis and Quantum Tunnelling of the Magnetisation in Dysprosium(III) Single Molecule Magnets

    Ortu, F., Reta, D., Ding, Y., Goodwin, C. A. P., Gregson, M., Mcinnes, E. J. L., Winpenny, R. E. P., Zheng, Y., Liddle, S., Mills, D. P. & Chilton, N. F., 2019, In : Dalton Transactions.

    Research output: Contribution to journalArticle

  9. Published

    Thorium- and Uranium-Azide Reductions: A Transient Dithorium-Nitride Versus Isolable Diuranium-Nitrides

    Du, J., King, D. M., Chatelain, L., Lu, E., Tuna, F., Mcinnes, E. J. L., Wooles, A., Laurent, M. & Liddle, S., 2019, In : Chemical Science.

    Research output: Contribution to journalArticle

  10. Published

    Trapping of a Highly Bent and Reduced Form of 2-Phosphaethynolate in a Mixed-Valence Diuranium-Triamidoamine Complex

    Liddle, S., Magnall, R., Balazs, G., Lu, E., Tuna, F., Wooles, A. & Scheer, M., 2019, In : Angewandte Chemie International Edition.

    Research output: Contribution to journalArticle

  11. 2018
  12. Published

    Uranyl-Tri-bis(silyl)amide Alkali Metal Contact- and Separated-Ion-Pair Complexes

    Cobb, P., Moulding, D., Ortu, F., Randall, S., Wooles, A., Natrajan, L. & Liddle, S., 4 Jun 2018, In : Inorganic Chemistry. 57, 11, p. 6571-6583 13 p.

    Research output: Contribution to journalArticle

  13. Published

    Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine- Titanium Complex

    Doyle, L., Wooles, A., Jenkins, L. C., Tuna, F., Mcinnes, E. & Liddle, S., 15 May 2018, In : Angewandte Chemie - International Edition. 57, 21, p. 6314-6318 4 p.

    Research output: Contribution to journalArticle

  14. Published

    Actinide-Pnictide (An-Pn) Bonds Spanning -Non-Metal, -Metalloid, and - Metal Combinations (An = U, Th; Pn = P, As, Sb, Bi)

    Rookes, T., Wildman, E., Balazs, G., Gardner, B., Wooles, A., Gregson, M., Tuna, F., Scheer, M. & Liddle, S., 22 Jan 2018, In : Angewandte Chemie - International Edition. 57, 5, p. 1332-1336 5 p.

    Research output: Contribution to journalArticle

  15. Published

    A Very Short Uranium(IV)-Rhodium(I) Bond with Net Double- Dative Bonding Character

    Lu, E., Wooles, A., Gregson, M., Cobb, P. & Liddle, S., 2018, In : Angewandte Chemie - International Edition.

    Research output: Contribution to journalArticle

  16. Published

    Actinide-Transition Metal Bonding in Heterobimetallic Uranium- and Thorium-Molybdenum Paddlewheel Complexes

    Ayres, A., Zegke, M., Ostrowski, J., Tuna, F., Mcinnes, E. J. L., Wooles, A. & Liddle, S., 2018, In : Chemical Communications.

    Research output: Contribution to journalArticle

  17. Published

    Silyl-Phosphino-Carbene Complexes of Uranium(IV)

    Lu, E., Boronski, J., Gregson, M., Wooles, A. J. & Liddle, S., 2018, In : Angewandte Chemie - International Edition.

    Research output: Contribution to journalArticle

  18. Published

    Uranium(III)-Carbon Multiple Bonding Supported by Arene δ-Bonding in Mixed-Valence Hexauranium Nanometre-Scale Rings

    Wooles, A., Mills, D., Tuna, F., Mcinnes, E., Law, G., Fuller, A., Kremer, F., Ridgway, M., Lewis, W., Gagliardi, L., Vlaisavljevich, B. & Liddle, S., 2018, In : Nature Communications. 9, 2097.

    Research output: Contribution to journalArticle

  19. 2017
  20. Published

    Crystalline Diuranium-Phosphinidiide and -μ-Phosphido Complexes with Symmetric and Asymmetric UPU Cores

    Rookes, T., Gardner, B., Balazs, G., Gregson, M., Tuna, F., Wooles, A., Scheer, M. & Liddle, S., 21 Aug 2017, In : Angewandte Chemie - International Edition. 56, 35, p. 10495-10500 6 p.

    Research output: Contribution to journalArticle

  21. Published
  22. Published

    Evidence for Single Metal Two Electron Oxidative Addition and Reductive Elimination at Uranium

    Gardner, B. M., Kefalidis, C. E., Lu, E., Patel, D., Mcinnes, E., Tuna, F., Wooles, A., Maron, L. & Liddle, S., 2017, In : Nature Communications. 8, 1898.

    Research output: Contribution to journalArticle

  23. Published

    Rare Earth- and Uranium-Mesoionic Carbenes: A New Class of f-Block Carbene Complex Derived from an N-Heterocyclic Olefin

    Liddle, S., Seed, J., Gregson, M., Tuna, F., Chilton, N., Wooles, A. & Mcinnes, E., 2017, In : Angewandte Chemie - International Edition.

    Research output: Contribution to journalArticle

  24. Published

    Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV)

    Stafford, H., Rookes, T., Wildman, E., Balazs, G., Wooles, A. J., Scheer, M. & Liddle, S., 2017, In : Angewandte Chemie - International Edition. 56, 26

    Research output: Contribution to journalArticle

  25. Published

    Terminal Uranium(V/VI)-Nitride Activation of Carbon Dioxide and Disulfide: Factors Governing Diverse and Well-Defined Cleavage and Redox Reactions

    Cleaves, P., Kefalidis, C. E., Gardner, B., Tuna, F., Mcinnes, E., Lewis, W., Maron, L. & Liddle, S., 2017, In : Chemistry: A European Journal. 23, 12

    Research output: Contribution to journalArticle

  26. Published

    The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

    Gregson, M., Lu, E., Mills, D., Tuna, F., Mcinnes, E., Hennig, C., Scheinost, A. C., McMaster, J., Lewis, W., Blake, A. J., Kerridge, A. & Liddle, S., 2017, In : Nature Communications. 8, 14137.

    Research output: Contribution to journalArticle

  27. Published

    Thorium(IV) alkyl synthesis from a thorium(III) cyclopentadienyl complex and an Nheterocyclic olefin

    Liu, J., Seed, J., Formanuik, A., Ortu, F., Wooles, A., Mills, D. & Liddle, S., 2017, In : Journal of Organometallic Chemistry.

    Research output: Contribution to journalArticle

  28. Published

    Triamidoamine Thorium-Arsenic Complexes with Parent Arsenide, Arsinidiide and Arsenido Structural Motifs

    Wildman, E., Balazs, G., Wooles, A., Scheer, M. & Liddle, S., 2017, In : Nature Communications. 8, 14769.

    Research output: Contribution to journalArticle

  29. Published

    Yttrium Methanide and Methanediide Bis(silyl)amide Complexes

    Ortu, F., Gregson, M., Wooles, A., Mills, D. & Liddle, S., 2017, In : Organometallics.

    Research output: Contribution to journalArticle

  30. 2016
  31. Published

    Catalyst: Nuclear Power in the 21st Century

    Kaltsoyannis, N. & Liddle, S., 10 Nov 2016, In : Chem. 1, 5, p. 652–662 11 p.

    Research output: Contribution to journalArticle

  32. Published

    Uranium Metalla-Allenes with Carbene Imido R2C=UIV=NR' Units (R = Ph2PNSiMe3; R' = CPh3): Alkali Metal-Mediated Push-Pull Effects with an Amido Auxiliary

    Lu, E., Tuna, F., Lewis, W., Kaltsoyannis, N. & Liddle, S., 1 Aug 2016, In : Chemistry - A European Journal. 22, 33, p. 11554–11558

    Research output: Contribution to journalArticle

  33. Published

    Uranium-Carbene-Imido Metalla-Allenes: Ancillary-Ligand-Controlled Cis-/Trans-Isomerisation and Assessment of Trans-Influence in the R2C=UIV=NR' Unit (R = Ph2PNSiMe3; R' = CPh3)

    Lu, E., Cooper, O. J., Tuna, F., Wooles, A., Kaltsoyannis, N. & Liddle, S., 1 Aug 2016, In : Chemistry - A European Journal. 22, 33, p. 11559–11563

    Research output: Contribution to journalArticle

  34. Published

    Uranium-Halide and -Azide Derivatives of the Sterically Demanding TriamidoamineLigand TrenTPS [TrenTPS = {N(CH2CH2NSiPh3)3}3-]

    Wildman, E., Ostrowski, J., King, D. M., Lewis, W. & Liddle, S., 1 Aug 2016, In : Polyhedron.

    Research output: Contribution to journalArticle

  35. Published

    A Monometallic Lanthanide Bis(methanediide) Single Molecule Magnet with a Large Energy Barrier and Complex Spin Relaxation Behaviour

    Gregson, M., Chilton, N. F., Ariciu, A-M., Tuna, F., Crowe, I., Lewis, W., Blake, A. J., Collison, D., Mcinnes, E., Winpenny, R. & Liddle, S. T., 1 Jul 2016, In : Chemical Science. 7, p. 155-165 10 p.

    Research output: Contribution to journalArticle

  36. Published

    Ligand design in f-Block Chemistry

    Liddle, S. T., Mills, D. P., Stradiotto, M. (ed.) & Lundgren, R. (ed.), 1 Jul 2016, Ligand Design in Metal Chemistry: Reactivity and Catalysis. Chichester, UK: John Wiley & Sons Ltd

    Research output: Chapter in Book/Report/Conference proceedingChapter

  37. Published

    Uranium halide complexes stabilized by a new sterically demanding tripodal tris(N-adamantylamidodimethylsilyl)methane ligand

    King, D. M., Gardner, B., Lewis, W. & Liddle, S., 24 May 2016, In : Journal of Coordination Chemistry. p. 1893-1903

    Research output: Contribution to journalArticle

  38. Published

    Neptunium and plutonium complexes with a sterically encumbered triamidoamine (TREN) scaffold

    Brown, J. L., Gaunt, A. J., King, D., Liddle, S., Reilly, S. D., Scott, B. L. & Wooles, A., 11 Mar 2016, In : Chemical Communications. p. 5428-5431

    Research output: Contribution to journalArticle

  39. Published

    Emergence of Comparable Covalency in Isostructural Cerium(IV)- and Uranium(IV)-Carbon Multiple Bonds

    Gregson, M., Lu, E., Liddle, S., Tuna, F., Mcinnes, E. J. L., Hennig, C., Scheinost, A. C., McMaster, J., Lewis, W., Blake, A. J. & Kerridge, A., 4 Feb 2016, In : Chemical Science. 7, 5, p. 3286 3297 p.

    Research output: Contribution to journalArticle

  40. Published

    Molecular and Electronic Structure of Terminal and Alkali Metal-Capped Uranium(V)-Nitride Complexes

    King, D., Cleaves, P., Wooles, A., Gardner, B., Chilton, N., Tuna, F., Lewis, W., Mcinnes, E. & Liddle, S., 2016, In : Nature Communications. 7, 13773.

    Research output: Contribution to journalArticle

  41. Published

    Thorium Phosphorus Triamidoamine Complexes Containing Th-P Single and Multiple Bond Interactions

    Wildman, E., Balazs, G., Wooles, A., Scheer, M. & Liddle, S., 2016, In : Nature Communications. 7, 12884.

    Research output: Contribution to journalArticle

  42. 2015
  43. Published

    Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex

    Gardner, B. M., Balazs, G., Scheer, M., Wooles, A. J., Tuna, F., Mcinnes, E. J. L., McMaster, J., Lewis, W., Blake, A. J. & Liddle, S. T., 28 Oct 2015, In : Angewandte Chemie (International Edition). 54, p. 15250-15254 4 p.

    Research output: Contribution to journalArticle

  44. Published

    Charge control of the inverse trans-influence

    La Pierre, H. S., Rosenzweig, M., Kosog, B., Hauser, C., Heinemann, F. W., Liddle, S. T. & Meyer, K., 25 Sep 2015, In : Chemical Communications. 51, 93, p. 16671-16674 3 p.

    Research output: Contribution to journalArticle

  45. Published

    The Renaissance of Non-Aqueous Uranium Chemistry

    Liddle, S. T., 20 Jul 2015, In : Angewandte Chemie (International Edition). 54, 30, p. 8604-8641 37 p.

    Research output: Contribution to journalArticle

  46. Published

    Synthesis and characterisation of halide, separated ion pair, and hydride cyclopentadienyl iron bis(diphenylphosphino)ethane derivatives

    Patel, D., Wooles, A., Cornish, A. D., Steven, L., Davies, E. S., Evans, D. J., McMaster, J., Lewis, W., Blake, A. J. & Liddle, S. T., 17 Jul 2015, In : Dalton Transactions. 44, 31, p. 14159-14177 19 p.

    Research output: Contribution to journalArticle

  47. Published

    Improving f-element single molecule magnets

    Liddle, S. T. & Van Slageren, J., 9 Jul 2015, In : Chemical Society Reviews. 44, 19, p. 6655-6669 15 p.

    Research output: Contribution to journalArticle

  48. Published

    Inverted sandwich arene complexes of uranium

    Liddle, S. T., 15 Jun 2015, In : Coordination Chemistry Reviews. 293-294, p. 211-227 16 p.

    Research output: Contribution to journalArticle

  49. Published

    Triamidoamine uranium(IV)–arsenic complexes containing one-, two- and threefold U–As bonding interactions

    Gardner, B., Balazs, G., Scheer, M., Tuna, F., Mcinnes, E., McMaster, J., Lewis, W., Blake, A. J. & Liddle, S., 15 Jun 2015, In : Nature Chemistry. 54, 7, p. 582-590

    Research output: Contribution to journalArticle

  50. Published

    Uranium triamidoamine chemistry

    Gardner, B. M. & Liddle, S. T., 2 Jun 2015, In : Chemical Communications. 51, 53, p. 10589-10607 19 p.

    Research output: Contribution to journalArticle

  51. Published

    Molecular Metal-Metal Bonds: Compounds, Synthesis, Properties

    Liddle, S. T., 6 May 2015, Weinheim, Germany: John Wiley & Sons Ltd. 568 p.

    Research output: Book/ReportAnthology

  52. Published

    Comments on reactions of oxide derivatives of uranium with hexachloropropene to give UCl4

    Patel, D., Wooles, A. J., Hashem, E., Omorodion, H., Baker, R. J. & Liddle, S. T., 14 Apr 2015, In : New Journal of Chemistry. 39, 10, p. 7559-7562 4 p.

    Research output: Contribution to journalArticle

  53. Published

    Actinide Single Molecule Magnets

    Liddle, S. T. & Van Slageren, J., 11 Mar 2015, Lanthanides and Actinides in Molecular Magnetism. Weinheim, Germany: John Wiley & Sons Ltd

    Research output: Chapter in Book/Report/Conference proceedingChapter

  54. Published

    Covalent Uranium Carbene Chemistry

    Gregson, M., Wooles, A. J., Cooper, O. J. & Liddle, S. T., Mar 2015, In : Comments on Inorganic Chemistry. 35, 5, p. 262-294 32 p.

    Research output: Contribution to journalArticle

  55. Published

    Thorium Triamidoamine Complexes: Synthesis of an Unusual Dinuclear Tuck-in-Tuck-over Thorium Metallacycle Featuring the Longest Known Thorium−σ-Alkyl Bond

    Gardner, B. M., Lewis, W., Blake, A. J. & Liddle, S. T., 26 Jan 2015, In : Organometallics. 34, 11, p. 2386-2394 9 p.

    Research output: Contribution to journalArticle

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