Dr Nicholas ChiltonMRSC

Senior Lecturer

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ORCID: 0000-0002-8604-0171
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Publications

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  1. Published

    [M2 IIIM3 II]n+ trigonal bipyramidal cages based on diamagnetic and paramagnetic metalloligands

    Sanz, S., O'Connor, H. M., Martí-Centelles, V., Comar, P., Pitak, M. B., Coles, S. J., Lorusso, G., Palacios, E., Evangelisti, M., Baldansuren, A., Chilton, N. F., Weihe, H., McInnes, E. J. L., Lusby, P. J., Piligkos, S. & Brechin, E. K., 2017, In : Chemical Science. 8, 8, p. 5526-5535 10 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/c7sc00487g
  2. Published

    {PHI}: A powerful new program for the analysis of anisotropic monomeric and exchange-coupled polynuclear d- and f-block complexes

    Chilton, N. F., Anderson, R. P., Turner, L. D., Soncini, A. & Murray, K. S., May 2013, In : Journal of Computational Chemistry. 34, 13, p. 1164-1175 12 p.

    Research output: Contribution to journal › Article

    DOI: 10.1002/jcc.23234
  3. Published

    A {CrIII2DyIII2} Single-Molecule Magnet: Enhancing the Blocking Temperature through 3d Magnetic Exchange

    Langley, S. K., Wielechowski, D. P., Vieru, V., Chilton, N. F., Moubaraki, B., Abrahams, B. F., Chibotaru, L. F. & Murray, K. S., 17 Sep 2013, In : Angewandte Chemie (International Edition). 52, 46, p. 12014-12019 5 p.

    Research output: Contribution to journal › Article

    DOI: 10.1002/anie.201306329
  4. Published

    A Bis-Monophospholyl Dysprosium Cation Showing Magnetic Hysteresis at 48 Kelvin

    Evans, P., Reta, D., Whitehead, G. F. S., Chilton, N. F. & Mills, D. P., 2019, In : Journal of the American Chemical Society.

    Research output: Contribution to journal › Article

    DOI: 10.1021/jacs.9b11515
  5. Published

    A Family of {CrIII2LnIII2 Butterfly Complexes: Effect of the Lanthanide Ion on the Single-Molecule Magnet Properties

    Langley, S. K., Wielechowski, D. P., Chilton, N. F., Moubaraki, B. & Murray, K. S., Nov 2015, In : Inorganic Chemistry: including bioinorganic chemistry . 54, 21, p. 10497-10503 7 p.

    Research output: Contribution to journal › Article

    DOI: 10.1021/acs.inorgchem.5b01999
  6. Published

    A high nuclearity mixed valence \{Mn$_{\textrm{32}}$\} complex

    Langley, S. K., Stott, R. A., Chilton, N. F., Moubaraki, B. & Murray, K. S., Apr 2011, In : Chemical Communications. 47, 22

    Research output: Contribution to journal › Article

    DOI: 10.1039/c1cc00035g
  7. Published

    A Large Barrier Single-Molecule Magnet Without Magnetic Memory

    Giansiracusa, M., Al-Badran, S., Kostopoulos, A., Whitehead, G., Collison, D., Tuna, F., Winpenny, R. & Chilton, N., 2019, In : Dalton Transactions.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C9DT01791G
  8. Published

    A Low-Symmetry Dysprosium Metallocene Single-Molecule Magnet with a High Anisotropy Barrier

    Pugh, T., Chilton, N. & Layfield, R., 2016, In : Angewandte Chemie (International Edition).

    Research output: Contribution to journal › Article

    DOI: 10.1002/anie.201604346
  9. Published

    A Monometallic Lanthanide Bis(methanediide) Single Molecule Magnet with a Large Energy Barrier and Complex Spin Relaxation Behaviour

    Gregson, M., Chilton, N. F., Ariciu, A-M., Tuna, F., Crowe, I., Lewis, W., Blake, A. J., Collison, D., Mcinnes, E., Winpenny, R. & Liddle, S. T., 1 Jul 2016, In : Chemical Science. 7, p. 155-165 10 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C5SC03111G
  10. Published

    An electrostatic model for the determination of magnetic anisotropy in dysprosium complexes

    Chilton, N. F., Collison, D., McInnes, E. JL., Winpenny, R. EP. & Soncini, A., Oct 2013, In : Nature Communications. 4, 4, 2551.

    Research output: Contribution to journal › Article

    DOI: 10.1038/ncomms3551
  11. Published

    Analysis of Lanthanide-Radical Magnetic Interactions in Ce(III) 2,2′-Bipyridyl Complexes

    Ortu, F., Liu, J., Burton, M., Fowler, J. M., Formanuik, A., Boulon, M-E., Chilton, N. & Mills, D., 6 Mar 2017, In : Inorganic Chemistry. 56, 5, p. 2496–2505 10 p.

    Research output: Contribution to journal › Article

    DOI: 10.1021/acs.inorgchem.6b02683
  12. Published

    Anisotropy barrier enhancement via ligand substitution in tetranuclear \{Co$^{\textrm{{III}}}$$_{\textrm{2}}$Ln$^{\textrm{{III}}}$$_{\textrm{2}}$\} single molecule magnets

    Langley, S. K., Chilton, N. F., Moubaraki, B. & Murray, K. S., Jul 2013, In : Chemical Communications. 49, 62, p. 6965-6967 3 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C3CC44037K
  13. Published

    Antimony-ligated dysprosium single-molecule magnets as catalysts for stibine dehydrocoupling

    Pugh, T., Chilton, N. & Layfield, R., 2017, In : Chemical Science. 8, p. 2073-2080 8 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C6SC04465D
  14. Published

    Assessing Crystal Field and Magnetic Interactions in Diuranium-­‐μ-­‐ Chalcogenide Triamidoamine Complexes With UIV-­‐E-­‐UIV Cores (E = S, Se, Te): Implications for Determining the Presence or Absence of Actinide-­‐Actinide Magnetic Exchange

    Gardner, B., King, D. M., Tuna, F., Wooles, A., Chilton, N. & Liddle, S., 2017, In : Chemical Science. 8, p. 6207-6217 10 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/c7sc01998j
  15. Published

    Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies

    Hawes, C. S., Chilton, N. F., Moubaraki, B., Knowles, G. P., Chaffee, A. L., Murray, K. S., Batten, S. R. & Turner, D. R., Oct 2015, In : Dalton Transactions. 44, 40, p. 17494-17507 14 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C5DT02323H
  16. Published

    Correlating Blocking Temperatures with Relaxation Mechanisms in Monometallic Single-Molecule Magnets with High Energy Barriers (Ueff > 600 K)

    Winpenny, R. E. P., Chilton, N. F., Giansiracusa, M., Collison, D. & Kostopoulos, A., 2019, In : Chemical Communications.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C9CC02421B
  17. Published

    Crown-linked dipyridylamino-triazine ligands and their spin-crossover iron(ii) derivatives: magnetism, photomagnetism and cooperativity

    Scott, H. S., Ross, T. M., Chilton, N. F., Gass, I. A., Moubaraki, B., Chastanet, G., Paradis, N., L??tard, J-F., Vignesh, K. R., Rajaraman, G., Batten, S. R. & Murray, K. S., Aug 2013, In : Dalton Transactions. 42, 47

    Research output: Contribution to journal › Article

    DOI: 10.1039/c3dt51839f
  18. Published

    Cu(II) coordination polymers as vehicles in the A3 coupling

    Loukopoulos, E., Kallitsakis, M., Tsoureas, N., Abdul-Sada, A., Chilton, N., Lykakis, I. N. & Kostakis, G. E., 2017, In : Inorganic Chemistry. 56, 9

    Research output: Contribution to journal › Article

    DOI: 10.1021/acs.inorgchem.6b03084
  19. Published

    Design Criteria for High-Temperature Single-Molecule Magnets

    Chilton, N. F., Feb 2015, In : Inorganic Chemistry: including bioinorganic chemistry . 54, 5, p. 2097-2099 3 p.

    Research output: Contribution to journal › Article

    DOI: 10.1021/acs.inorgchem.5b00089
  20. Published

    Di- and Tetranuclear Complexes of Bis-Tetradentate Pyrimidine-Based Ligands with All-Methylene- Versus Mixed Methylene/Ethylene-Linked Arms

    Gobeze, W. A., Milway, V. A., Chilton, N. F., Moubaraki, B., Murray, K. S. & Brooker, S., Jul 2013, In : European Journal of Inorganic Chemistry. 2013, 25, p. 4485-4498 14 p.

    Research output: Contribution to journal › Article

    DOI: 10.1002/ejic.201300368
  21. Published

    Dichlorido-bridged dinuclear Dy(III) single-molecule magnet with an effective energy barrier larger than 600 K

    Han, T., Ding, Y., Li, Z., Yu, K., Zhai, Y., Chilton, N. F. & Zheng, Y., 2019, In : Chemical Communications.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C9CC02436K
  22. Published

    Direct measurement of dysprosium(III)˙˙˙dysprosium(III) interactions in a single-molecule magnet

    Moreno Pineda, E., Chilton, N. F., Marx, R., Dorfel, M., Sells, D. O., Neugebauer, P., Jiang, S-D., Collison, D., van Slageren, J., Mcinnes, E. & Winpenny, R. EP., Oct 2014, In : Nature Communications. 5, p. 5243-5243 1 p.

    Research output: Contribution to journal › Article

    DOI: 10.1038/ncomms6243
  23. Published

    Dispersion Force Stabilized Two-Coordinate Transition Metal???Amido Complexes of the ???N({SiMe}$_{\textrm{3}}$)Dipp (Dipp = C$_{\textrm{6}}$H$_{\textrm{3}}$-2,6-Pr$^{\textrm{i}}$$_{\textrm{2}}$) Ligand: Structural, Spectroscopic, Magnetic, and Computational Studies

    Lin, C-Y., Guo, J-D., Fettinger, J. C., Nagase, S., Grandjean, F., Long, G. J., Chilton, N. F. & Power, P. P., Nov 2013, In : Inorganic Chemistry: including bioinorganic chemistry . 52, 23, p. 13584-13593 10 p.

    Research output: Contribution to journal › Article

    DOI: 10.1021/ic402105m
  24. Published

    Electronic Structures of Bent Lanthanide(III) Complexes with Two N-Donor Ligands

    Nicholas, H., Vonci, M., Goodwin, C. A. P., Loo, S. W., Murphy, S., Cassim, D., Winpenny, R. E. P., Mcinnes, E. J. L., Chilton, N. F. & Mills, D. P., 2019, In : Chemical Science.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C9SC03431E
  25. Published

    Engineering electronic structure to prolong relaxation times in molecular qubits by minimising orbital angular momentum

    Ariciu, A-M., Woen, D. H., Huh, D. N., Nodaraki, L., Kostopoulos, A., Goodwin, C., Chilton, N., Mcinnes, E., Winpenny, R., Evans, W. J. & Tuna, F., 2019, In : Nature Communications.

    Research output: Contribution to journal › Article

    DOI: 10.1038/s41467-019-11309-3
  26. Published

    Evidence of Slow Magnetic Relaxation in Co(AcO)2(py)2(H2O)2

    Walsh, J. P. S., Graeme Bowling, Ariciu, A-M., Jailani, N., Chilton, N., Paul G.Waddell, Collison, D., Tuna, F. & Lee J. Higham, 2016, In : Magnetochemistry. 2, 2, p. 1-10 11 p., 23.

    Research output: Contribution to journal › Article

    DOI: 10.3390/magnetochemistry2020023
  27. Published

    Exploring the coordination capabilities of a family of flexible benzotriazole-based ligands using Cobalt (II) sources

    Loukopoulos, E., Chilton, N., Abdul-Sada, A. & Kostakis, G. E., 2017, In : Crystal Growth and Design.

    Research output: Contribution to journal › Article

    DOI: 10.1021/acs.cgd.7b00200
  28. Published

    Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes

    Mason, K., Harnden, A. C., Patrick, C. W., Poh, A. W. J., Batsanov, A. S., Suturina, E. A., Vonci, M., McInnes, E. J. L., Chilton, N. F. & Parker, D., 26 Jul 2018, In : Chemical communications (Cambridge, England). 54, 61, p. 8486-8489 4 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/c8cc04995e
  29. Published

    Fast magnetic relaxation in an octahedral dysprosium tetramethyl-aluminate complex

    König, S. N., Chilton, N. F., Maichle-Mössmer, C., Pineda, E. M., Pugh, T., Anwander, R. & Layfield, R. A., 28 Feb 2014, In : Dalton Transactions. 43, 8, p. 3035-3038 4 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/c3dt52337c 10.1039/C3DT52337C
  30. Published

    Field- and temperature-dependent quantum tunnelling of the magnetisation in a large barrier single-molecule magnet

    Ding, Y. S., Yu, K. X., Reta, D., Ortu, F., Winpenny, R., Zheng, Y-Z. & Chilton, N., 7 Aug 2018, In : Nature Communications. 9

    Research output: Contribution to journal › Article

    DOI: 10.1038/s41467-018-05587-6
  31. Published

    Heterometallic Tetranuclear [Ln$^{\textrm{{III}}}$$_{\textrm{2}}$Co$^{\textrm{{III}}}$$_{\textrm{2}}$] Complexes Including Suppression of Quantum Tunneling of Magnetization in the [Dy$^{\textrm{{III}}}$$_{\textrm{2}}$Co$^{\textrm{{III}}}$$_{\textrm{2}}$] Single Molecule Magnet

    Langley, S. K., Chilton, N. F., Ungur, L., Moubaraki, B., Chibotaru, L. F. & Murray, K. S., Oct 2012, In : Inorganic Chemistry: including bioinorganic chemistry . 51, p. 11873-11881 9 p.

    Research output: Contribution to journal › Article

    DOI: 10.1021/ic301784m
  32. Published

    Investigation into the Effects of a Trigonal Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)

    Goodwin, C., Chilton, N., Natrajan, L., Boulon, M-E., Ziller, J. W., Evans, W. J. & Mills, D., 1 May 2017, In : Inorganic Chemistry.

    Research output: Contribution to journal › Article

    DOI: 10.1021/acs.inorgchem.7b00664
  33. Published

    Iron Precatalysts with Bulky Tri(tert-butyl)cyclopentadienyl Ligands for the Dehydrocoupling of Dimethylamine-Borane

    Turner, J., Chilton, N. F., Kumar, A., Colebatch, A. L., Whittell, G. R., Sparkes, H. A., Weller, A. S. & Manners, I., 20 Sep 2018, In : Chemistry - A European Journal. 24, 53, p. 14127-14136 10 p.

    Research output: Contribution to journal › Article

    DOI: 10.1002/chem.v24.53
  34. Published

    Iron({II}) Complexes of Two Amine/Imine N$_{\textrm{5}}$ Chelate Ligands Containing a 1,4-Diazepane Core ??? To Crossover or Not To Crossover

    Schmidt, M., Wiedemann, D., Moubaraki, B., Chilton, N. F., Murray, K. S., Vignesh, K. R., Rajaraman, G. & Grohmann, A., Feb 2013, In : European Journal of Inorganic Chemistry. 2013, 5-6, p. 958-967 10 p.

    Research output: Contribution to journal › Article

    DOI: 10.1002/ejic.201201149
  35. Published

    Lanthanide-induced relaxation anisotropy

    Suturina, E. A., Mason, K., Geraldes, C. F. G. C., Chilton, N., Parker, D. & Kuprov, I., 14 Jul 2018, In : Physical Chemistry Chemical Physics. 26

    Research output: Contribution to journal › Article

    DOI: 10.1039/C8CP01332B
  36. Published

    Large Zero-Field Splittings of the Ground Spin State Arising from Antisymmetric Exchange Effects in Heterometallic Triangles

    Magee, S. A., Sproules, S., Barra, A-L., Timco, G. A., Chilton, N. F., Collison, D., Winpenny, R. E. P. & McInnes, E. J. L., Apr 2014, In : Angewandte Chemie International Edition. 53, 21, p. 5310-5313 4 p.

    Research output: Contribution to journal › Article

    DOI: 10.1002/anie.201400655
  37. Published

    Ligand field influence on the electronic and magnetic properties of quasi-linear two-coordinate iron(ii) complexes

    Chilton, N. F., Lei, H., Bryan, A. M., Grandjean, F., Long, G. J. & Power, P. P., 2015, In : Dalton Trans.. 44, p. 11202-11211 10 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C5DT01589H
  38. Published

    Light Lanthanide Metallocenium Cations Exhibiting Weak Equatorial Anion Interactions

    Liu, J., Reta, D., Cleghorn, J. A., Yeoh, Y. X., Ortu, F., Goodwin, C., Chilton, N. & Mills, D., 2019, In : Chemistry: A European Journal .

    Research output: Contribution to journal › Article

    DOI: 10.1002/chem.201901167
  39. Published

    LnIII2MnIII2 heterobimetallic “butterfly” complexes displaying antiferromagnetic coupling (Ln = Eu, Gd, Tb, Er)

    Chesman, A. S. R., Turner, D. R., Berry, K. J., Chilton, N. F., Moubaraki, B., Murray, K. S., Deacon, G. B. & Batten, S. R., 4 Jul 2012, In : Dalton Transactions. 41, 37, p. 11402-11412 10 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C2DT31144E
  40. Published

    Magnetic properties of octa- and heptadeca-nuclear heterometallic Co$^{\textrm{{II}}}$-Ln$^{\textrm{{III}}}$ complexes derived from the ligand 6-chloro-2-hydroxypyridine

    Langley, S. K., Chilton, N. F., Moubaraki, B. & Murray, K. S., Dec 2013, In : Polyhedron. 66, p. 48-55 8 p.

    Research output: Contribution to journal › Article

    DOI: 10.1016/j.poly.2013.02.007
  41. Published

    Measurement of magnetic exchange in asymmetric lanthanide dimetallics: towards a transferable theoretical framework

    Giansiracusa, M., Moreno Pineda, E., Hussain, R., Marx, R., Prada, M. M., Neugebauer, P., Al-Badran, S., Collison, D., Tuna, F., Slageren, J. V., Carretta, S., Guidi, T., Mcinnes, E., Winpenny, R. & Chilton, N., 2018, In : American Chemical Society. Journal .

    Research output: Contribution to journal › Article

    DOI: 10.1021/jacs.7b10714
  42. Published

    Measuring spin···spin interactions between heterospins in a hybrid [2]rotaxane

    Boulon, M-E., Fernandez Mato, A., Moreno Pineda, E., Chilton, N., Timco, G., Fielding, A. & Winpenny, R., 27 Mar 2017, In : Angewandte Chemie - International Edition. 56, 14, p. 3876–3879

    Research output: Contribution to journal › Article

    DOI: 10.1002/anie.201612249
  43. Published

    Metallacrowns as templates for diabolo-like {LnCu8} complexes with nearly perfect square antiprismatic geometry

    Zhou, G-J., Han, T., Ding, Y. S., Chilton, N. & Zheng, Y-Z., 2017, In : Chemistry: A European Journal .

    Research output: Contribution to journal › Article

    DOI: 10.1002/chem.201703830
  44. Published

    Modular [(Fe8M6II)-M-III](&ITn&IT+)(M-II = Pd, Co, Ni, Cu) Coordination Cages

    Sanz, S., O'Connor, H. M., Comar, P., Baldansuren, A., Pitak, M. B., Coles, S. J., Weihe, H., Chilton, N. F., McInnes, E. J. L., Lusby, P. J., Piligkos, S. & Brechin, E. K., 2 Apr 2018, In : Inorganic Chemistry. 57, 7, p. 3500-3506

    Research output: Contribution to journal › Article

    DOI: 10.1021/acs.inorgchem.7b02674
  45. Published

    Modulation of slow magnetic relaxation by tuning magnetic exchange in \{Cr2Dy2\} single molecule magnets

    Langley, S. K., Wielechowski, D. P., Vieru, V., Chilton, N. F., Moubaraki, B., Chibotaru, L. F. & Murray, K. S., Jun 2014, In : Chemical Science. 5, 8, p. 3246-3256 11 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C4SC01239A
  46. Published

    Molecular and Electronic Structure of Terminal and Alkali Metal-Capped Uranium(V)-Nitride Complexes

    King, D., Cleaves, P., Wooles, A., Gardner, B., Chilton, N., Tuna, F., Lewis, W., Mcinnes, E. & Liddle, S., 2016, In : Nature Communications. 7, 13773.

    Research output: Contribution to journal › Article

    DOI: 10.1038/ncomms13773
  47. Published

    Molecular and Electronic Structures of Donor-Functionalized Dysprosium Pentadienyl Complexes

    Day, B. M., Chilton, N. F. & Layfield, R. A., 2015, In : Dalton Transactions. 44, 16, p. 7109-7113 4 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/C5DT00346F
  48. Published

    Molecular coolers: The case for [Cu$^{\textrm{{II}}}$$_{\textrm{5}}$Gd$^{\textrm{{III}}}$$_{\textrm{4}}$]

    Langley, S. K., Chilton, N. F., Moubaraki, B., Hooper, T., Brechin, E. K., Evangelisti, M. & Murray, K. S., Apr 2011, In : Chemical Science. 2, 6, p. 1166-1169 4 p.

    Research output: Contribution to journal › Article

    DOI: 10.1039/c1sc00038a
  49. Published

    Molecular magnetic hysteresis at 60 K in dysprosocenium

    Goodwin, C., Ortu, F., Reta, D., Chilton, N. & Mills, D., 24 Aug 2017, In : Nature. 548, p. 439-442

    Research output: Contribution to journal › Article

    DOI: 10.1038/nature23447
  50. Published

    Molecules Designed to Contain Two Weakly Coupled Spins with a Photo-switchable Spacer

    Aromi, G., Salinas Uber, J., Estrader, M., Garcia, J., Lloyd-Williams, P., Sadurní, A., Dengler, D., van Slageren, J., Chilton, N., Roubeau, O., Teat, S. J. & Ribas-Ariño, J., 2017, In : Chemistry: A European Journal.

    Research output: Contribution to journal › Article

    DOI: 10.1002/chem.201702171
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Research Explorer downloads

333
A Monometallic Lanthanide Bis(methanediide) Single Molecule Magnet with a Large Energy Barrier and Complex Spin Relaxation Behaviour

Research output: Contribution to journal › Article

255
Molecular magnetic hysteresis at 60 K in dysprosocenium

Research output: Contribution to journal › Article

87
Measuring spin···spin interactions between heterospins in a hybrid [2]rotaxane

Research output: Contribution to journal › Article

77
Strong Exchange Coupling in a Trimetallic Radical-Bridged Cobalt(II)-Hexaazatrinaphthalene Complex

Research output: Contribution to journal › Article

64
Analysis of Lanthanide-Radical Magnetic Interactions in Ce(III) 2,2′-Bipyridyl Complexes

Research output: Contribution to journal › Article