Dr Nicholas ChiltonMRSC

Senior Lecturer

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Publications

  1. 2019
  2. Published

    Unravelling the Complexities of Pseudocontact Shift Analysis in Lanthanide Coordination Complexes of Differing Symmetry

    Harnden, A. C., Suturina, E. A., Batsanov, A. S., Senanayake, P. K., Fox, M. A., Mason, K., Vonci, M., McInnes, E. J. L., Chilton, N. F. & Parker, D., 22 Jul 2019, In : Angewandte Chemie - International Edition. 58, 30, p. 10290-10294 5 p.

    Research output: Contribution to journalArticle

  3. Published

    The Sensitivity of Magnetic Anisotropy in the Solid State for Lanthanide Complexes with Small Crystal Field Splitting

    Vonci, M., Mason, K., Neil, E., Yufit, D. S., Mcinnes, E., Parker, D. & Chilton, N., 6 May 2019, In : Inorganic Chemistry.

    Research output: Contribution to journalArticle

  4. Published

    A Large Barrier Single-Molecule Magnet Without Magnetic Memory

    Giansiracusa, M., Al-Badran, S., Kostopoulos, A., Whitehead, G., Collison, D., Tuna, F., Winpenny, R. & Chilton, N., 2019, In : Dalton Transactions.

    Research output: Contribution to journalArticle

  5. Published

    Correlating Blocking Temperatures with Relaxation Mechanisms in Monometallic Single-Molecule Magnets with High Energy Barriers (Ueff > 600 K)

    Winpenny, R. E. P., Chilton, N. F., Giansiracusa, M., Collison, D. & Kostopoulos, A., 2019, In : Chemical Communications.

    Research output: Contribution to journalArticle

  6. Published

    Dichlorido-bridged dinuclear Dy(III) single-molecule magnet with an effective energy barrier larger than 600 K

    Han, T., Ding, Y., Li, Z., Yu, K., Zhai, Y., Chilton, N. F. & Zheng, Y., 2019, In : Chemical Communications.

    Research output: Contribution to journalArticle

  7. Published

    Electronic Structures of Bent Lanthanide(III) Complexes with Two N-Donor Ligands

    Nicholas, H., Vonci, M., Goodwin, C. A. P., Loo, S. W., Murphy, S., Cassim, D., Winpenny, R. E. P., Mcinnes, E. J. L., Chilton, N. F. & Mills, D. P., 2019, In : Chemical Science.

    Research output: Contribution to journalArticle

  8. Published

    Engineering electronic structure to prolong relaxation times in molecular qubits by minimising orbital angular momentum

    Ariciu, A-M., Woen, D. H., Huh, D. N., Nodaraki, L., Kostopoulos, A., Goodwin, C., Chilton, N., Mcinnes, E., Winpenny, R., Evans, W. J. & Tuna, F., 2019, In : Nature Communications.

    Research output: Contribution to journalArticle

  9. Published

    Light Lanthanide Metallocenium Cations Exhibiting Weak Equatorial Anion Interactions

    Liu, J., Reta, D., Cleghorn, J. A., Yeoh, Y. X., Ortu, F., Goodwin, C., Chilton, N. & Mills, D., 2019, In : Chemistry: A European Journal .

    Research output: Contribution to journalArticle

  10. Published

    Periodic trends and hidden dynamics of magnetic properties in three series of triazacyclononane lanthanide complexes

    Parker, D., Suturina, E., Mason, K., Botta, M., Carniato, F., Kuprov, I., Chilton, N. F., Vonci, M. & Mcinnes, E. J. L., 2019, In : Dalton Transactions.

    Research output: Contribution to journalArticle

  11. Published

    Slow magnetic relaxation in a {EuCu5} metallacrown

    Wang, J., Ruan, Z., Li, Q., Chen, Y., Huang, G., Liu, J., Reta, D., Chilton, N. F., Wang, Z. & Tong, M., 2019, In : Dalton Transactions. 48, 5, p. 1686-1692

    Research output: Contribution to journalArticle

  12. Published

    Studies of Hysteresis and Quantum Tunnelling of the Magnetisation in Dysprosium(III) Single Molecule Magnets

    Ortu, F., Reta, D., Ding, Y., Goodwin, C. A. P., Gregson, M., Mcinnes, E. J. L., Winpenny, R. E. P., Zheng, Y., Liddle, S., Mills, D. P. & Chilton, N. F., 2019, In : Dalton Transactions.

    Research output: Contribution to journalArticle

  13. Published

    Uncertainty estimates for magnetic relaxation times and magnetic relaxation parameters

    Reta, D. & Chilton, N., 2019, In : Physical Chemistry Chemical Physics: high quality research in physical chemistry, chemical physics and biophysical chemistry.

    Research output: Contribution to journalArticle

  14. 2018
  15. Published

    Iron Precatalysts with Bulky Tri(tert-butyl)cyclopentadienyl Ligands for the Dehydrocoupling of Dimethylamine-Borane

    Turner, J., Chilton, N. F., Kumar, A., Colebatch, A. L., Whittell, G. R., Sparkes, H. A., Weller, A. S. & Manners, I., 20 Sep 2018, In : Chemistry - A European Journal. 24, 53, p. 14127-14136 10 p.

    Research output: Contribution to journalArticle

  16. Published

    Field- and temperature-dependent quantum tunnelling of the magnetisation in a large barrier single-molecule magnet

    Ding, Y. S., Yu, K. X., Reta, D., Ortu, F., Winpenny, R., Zheng, Y-Z. & Chilton, N., 7 Aug 2018, In : Nature Communications. 9

    Research output: Contribution to journalArticle

  17. Published

    Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes

    Mason, K., Harnden, A. C., Patrick, C. W., Poh, A. W. J., Batsanov, A. S., Suturina, E. A., Vonci, M., McInnes, E. J. L., Chilton, N. F. & Parker, D., 26 Jul 2018, In : Chemical communications (Cambridge, England). 54, 61, p. 8486-8489 4 p.

    Research output: Contribution to journalArticle

  18. Published

    Lanthanide-induced relaxation anisotropy

    Suturina, E. A., Mason, K., Geraldes, C. F. G. C., Chilton, N., Parker, D. & Kuprov, I., 14 Jul 2018, In : Physical Chemistry Chemical Physics. 26

    Research output: Contribution to journalArticle

  19. Published

    Self-assembly of a mixed-valence FeII-FeIII tetranuclear star

    Sertphon, D., Harding, P., Murray, K. S., Moubaraki, B., Chilton, N., Hill, S., Marbey, J., Adams, H., Davies, C. G., Jameson, G. N. L. & Harding, D. J., 7 Jun 2018, In : Dalton Transactions. 47, 21, p. 7118-7122

    Research output: Contribution to journalArticle

  20. Published

    Modular [(Fe8M6II)-M-III](&ITn&IT+)(M-II = Pd, Co, Ni, Cu) Coordination Cages

    Sanz, S., O'Connor, H. M., Comar, P., Baldansuren, A., Pitak, M. B., Coles, S. J., Weihe, H., Chilton, N. F., McInnes, E. J. L., Lusby, P. J., Piligkos, S. & Brechin, E. K., 2 Apr 2018, In : Inorganic Chemistry. 57, 7, p. 3500-3506

    Research output: Contribution to journalArticle

  21. Published

    Measurement of magnetic exchange in asymmetric lanthanide dimetallics: towards a transferable theoretical framework

    Giansiracusa, M., Moreno Pineda, E., Hussain, R., Marx, R., Prada, M. M., Neugebauer, P., Al-Badran, S., Collison, D., Tuna, F., Slageren, J. V., Carretta, S., Guidi, T., Mcinnes, E., Winpenny, R. & Chilton, N., 2018, In : American Chemical Society. Journal .

    Research output: Contribution to journalArticle

  22. Published

    Terbocenium: completing a heavy lanthanide metallocenium cation family with an alternative anion abstraction strategy

    Goodwin, C. A. P., Reta, D., Ortu, F., Liu, J., Chilton, N. & Mills, D., 2018, In : Chemical Communications.

    Research output: Contribution to journalArticle

  23. Published
  24. 2017
  25. Published

    Molecular magnetic hysteresis at 60 K in dysprosocenium

    Goodwin, C., Ortu, F., Reta, D., Chilton, N. & Mills, D., 24 Aug 2017, In : Nature. 548, p. 439-442

    Research output: Contribution to journalArticle

  26. Published

    Investigation into the Effects of a Trigonal Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)

    Goodwin, C., Chilton, N., Natrajan, L., Boulon, M-E., Ziller, J. W., Evans, W. J. & Mills, D., 1 May 2017, In : Inorganic Chemistry.

    Research output: Contribution to journalArticle

  27. Published

    Measuring spin···spin interactions between heterospins in a hybrid [2]rotaxane

    Boulon, M-E., Fernandez Mato, A., Moreno Pineda, E., Chilton, N., Timco, G., Fielding, A. & Winpenny, R., 27 Mar 2017, In : Angewandte Chemie - International Edition. 56, 14, p. 3876–3879

    Research output: Contribution to journalArticle

  28. Published

    Analysis of Lanthanide-Radical Magnetic Interactions in Ce(III) 2,2′-Bipyridyl Complexes

    Ortu, F., Liu, J., Burton, M., Fowler, J. M., Formanuik, A., Boulon, M-E., Chilton, N. & Mills, D., 6 Mar 2017, In : Inorganic Chemistry. 56, 5, p. 2496–2505 10 p.

    Research output: Contribution to journalArticle

  29. Published

    [M2 IIIM3 II]n+ trigonal bipyramidal cages based on diamagnetic and paramagnetic metalloligands

    Sanz, S., O'Connor, H. M., Martí-Centelles, V., Comar, P., Pitak, M. B., Coles, S. J., Lorusso, G., Palacios, E., Evangelisti, M., Baldansuren, A., Chilton, N. F., Weihe, H., McInnes, E. J. L., Lusby, P. J., Piligkos, S. & Brechin, E. K., 2017, In : Chemical Science. 8, 8, p. 5526-5535 10 p.

    Research output: Contribution to journalArticle

  30. Published

    Antimony-ligated dysprosium single-molecule magnets as catalysts for stibine dehydrocoupling

    Pugh, T., Chilton, N. & Layfield, R., 2017, In : Chemical Science. 8, p. 2073-2080 8 p.

    Research output: Contribution to journalArticle

  31. Published
  32. Published

    Cu(II) coordination polymers as vehicles in the A3 coupling

    Loukopoulos, E., Kallitsakis, M., Tsoureas, N., Abdul-Sada, A., Chilton, N., Lykakis, I. N. & Kostakis, G. E., 2017, In : Inorganic Chemistry. 56, 9

    Research output: Contribution to journalArticle

  33. Published

    Exploring the coordination capabilities of a family of flexible benzotriazole-based ligands using Cobalt (II) sources

    Loukopoulos, E., Chilton, N., Abdul-Sada, A. & Kostakis, G. E., 2017, In : Crystal Growth and Design.

    Research output: Contribution to journalArticle

  34. Published

    Metallacrowns as templates for diabolo-like {LnCu8} complexes with nearly perfect square antiprismatic geometry

    Zhou, G-J., Han, T., Ding, Y. S., Chilton, N. & Zheng, Y-Z., 2017, In : Chemistry: A European Journal .

    Research output: Contribution to journalArticle

  35. Published

    Molecules Designed to Contain Two Weakly Coupled Spins with a Photo-switchable Spacer

    Aromi, G., Salinas Uber, J., Estrader, M., Garcia, J., Lloyd-Williams, P., Sadurní, A., Dengler, D., van Slageren, J., Chilton, N., Roubeau, O., Teat, S. J. & Ribas-Ariño, J., 2017, In : Chemistry: A European Journal.

    Research output: Contribution to journalArticle

  36. Published

    Rare Earth- and Uranium-Mesoionic Carbenes: A New Class of f-Block Carbene Complex Derived from an N-Heterocyclic Olefin

    Liddle, S., Seed, J., Gregson, M., Tuna, F., Chilton, N., Wooles, A. & Mcinnes, E., 2017, In : Angewandte Chemie - International Edition.

    Research output: Contribution to journalArticle

  37. Published

    Rationalisation of anomalous pseudo-contact shifts and their solvent dependence in a series of C3-symmetric lanthanide complexes

    Vonci, M., Mason, K., Suturina, E. A., Frawley, A. T., Worswick, S. G., Kuprov, I., Parker, D., Mcinnes, E. & Chilton, N., 2017, In : American Chemical Society. Journal .

    Research output: Contribution to journalArticle

  38. Published

    Synthesis and Electronic Structures of Heavy Lanthanide Metallocenium Cations

    Goodwin, C. A. P., Reta, D., Ortu, F., Chilton, N. & Mills, D., 2017, In : American Chemical Society. Journal .

    Research output: Contribution to journalArticle

  39. 2016
  40. Published

    On Approaching The Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal DyIII Single-Molecule Magnet

    Ding, Y. S., Chilton, N., Winpenny, R. & Zheng, Y-Z., 21 Dec 2016, In : Angewandte Chemie - International Edition. 55, 52, p. 16071-16074 4 p.

    Research output: Contribution to journalArticle

  41. Published

    A Monometallic Lanthanide Bis(methanediide) Single Molecule Magnet with a Large Energy Barrier and Complex Spin Relaxation Behaviour

    Gregson, M., Chilton, N. F., Ariciu, A-M., Tuna, F., Crowe, I., Lewis, W., Blake, A. J., Collison, D., Mcinnes, E., Winpenny, R. & Liddle, S. T., 1 Jul 2016, In : Chemical Science. 7, p. 155-165 10 p.

    Research output: Contribution to journalArticle

  42. Published

    Tetranuclear 3d/4f coordination clusters as highly efficient catalysts for Friedel Crafts alkylation

    Griffiths, K., Kumar, P., Akien, G. R., Chilton, N., Abdul-Sada, A., Tizzard, G. J., . Coles, S. J. & . Kostakis, G. E., 25 Jun 2016, In : Inorganic Chemistry: including bioinorganic chemistry . 52, 50, p. 7866-7869 4 p.

    Research output: Contribution to journalArticle

  43. Published

    Strong Exchange Coupling in a Trimetallic Radical-Bridged Cobalt(II)-Hexaazatrinaphthalene Complex

    Moilanen, J. O., Chilton, N., Day, B. M., Pugh, T. & Layfield, R. A., 10 Apr 2016, In : Angewandte Chemie (International Edition). 55, 18, p. 5521–5525

    Research output: Contribution to journalArticle

  44. Published

    A Low-Symmetry Dysprosium Metallocene Single-Molecule Magnet with a High Anisotropy Barrier

    Pugh, T., Chilton, N. & Layfield, R., 2016, In : Angewandte Chemie (International Edition).

    Research output: Contribution to journalArticle

  45. Published

    Evidence of Slow Magnetic Relaxation in Co(AcO)2(py)2(H2O)2

    Walsh, J. P. S., Graeme Bowling, Ariciu, A-M., Jailani, N., Chilton, N., Paul G.Waddell, Collison, D., Tuna, F. & Lee J. Higham, 2016, In : Magnetochemistry. 2, 2, p. 1-10 11 p., 23.

    Research output: Contribution to journalArticle

  46. Published

    Molecular and Electronic Structure of Terminal and Alkali Metal-Capped Uranium(V)-Nitride Complexes

    King, D., Cleaves, P., Wooles, A., Gardner, B., Chilton, N., Tuna, F., Lewis, W., Mcinnes, E. & Liddle, S., 2016, In : Nature Communications. 7, 13773.

    Research output: Contribution to journalArticle

  47. Published

    Physicochemical properties of near-linear Ln(II) bis-silylamide complexes (Ln = Sm, Eu, Tm, Yb)

    Goodwin, C., Chilton, N., Vettese, G. F., Moreno Pineda, E., Crowe, I., Ziller, J. W., Evans, W. J. & Mills, D., 2016, In : Inorganic Chemistry. 55, 20

    Research output: Contribution to journalArticle

  48. Published

    Three-Coordinate Iron(II) Expanded Ring N-Heterocyclic Car-bene Complexes

    Dunsford, J., Pugh, T., Shah, S., Evans, D., Chilton, N. & Ingleson, M., 2016, In : Organometallics.

    Research output: Contribution to journalArticle

  49. Published

    Unprecedented Hexagonal Bipyramidal Single-Ion Magnets Based on Metallacrowns

    Chilton, N., Li, Q-W., Wan, R-C., Chen, Y-C., Liu, J-L., Wang, L-F., Jia, J-H. & Tong, M-L., 2016, In : Chemical Communications.

    Research output: Contribution to journalArticle

  50. 2015
  51. Published

    A Family of {CrIII2LnIII2 Butterfly Complexes: Effect of the Lanthanide Ion on the Single-Molecule Magnet Properties

    Langley, S. K., Wielechowski, D. P., Chilton, N. F., Moubaraki, B. & Murray, K. S., Nov 2015, In : Inorganic Chemistry: including bioinorganic chemistry . 54, 21, p. 10497-10503 7 p.

    Research output: Contribution to journalArticle

  52. Published

    Coordination polymers from a highly flexible alkyldiamine-derived ligand: structure, magnetism and gas adsorption studies

    Hawes, C. S., Chilton, N. F., Moubaraki, B., Knowles, G. P., Chaffee, A. L., Murray, K. S., Batten, S. R. & Turner, D. R., Oct 2015, In : Dalton Transactions. 44, 40, p. 17494-17507 14 p.

    Research output: Contribution to journalArticle

  53. Published

    Spectroscopic and Crystal Field Consequences of Fluoride Binding by [Yb.DTMA]3+ in Aqueous Solution

    Blackburn, O. A., Chilton, N. F., Keller, K., Tait, C. E., Myers, W. K., McInnes, E. J. L., Kenwright, A. M., Beer, P. D., Timmel, C. R. & Faulkner, S., Sep 2015, In : Angewandte Chemie International Edition. 54, 37, p. 10783-10786 4 p.

    Research output: Contribution to journalArticle

  54. Published

    Salts of the two-coordinate homoleptic manganese({I}) dialkyl anion [{Mn}\{{C}({SiMe}3)3\}2]??? with quenched orbital magnetism

    Lin, C-Y., Fettinger, J. C., Chilton, N. F., Formanuik, A., Grandjean, F., Long, G. J. & Power, P. P., Aug 2015, In : Chemical Communications. 51, 68, p. 13275-13278 4 p.

    Research output: Contribution to journalArticle

  55. Published

    Single-molecule magnetism in \{{CoIII}2DyIII2\}-amine-polyalcohol-acetylacetonate complexes: effects of ligand replacement at the {DyIII} sites on the dynamics of magnetic relaxation

    Langley, S. K., Chilton, N. F., Moubaraki, B. & Murray, K. S., Aug 2015, In : Inorganic Chemistry Frontiers. 2, 9, p. 867-875 9 p.

    Research output: Contribution to journalArticle

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