Prof Eric Mcinnes

Professor of Inorganic Chemistry

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Publications

  1. 2019
  2. Accepted/In press

    Iodine adsorption in a redox-active metal-organic framework: electrical conductivity induced by host-guest charge-transfer

    Zhang, X., Silva, I. D., Fazzi, R., Sheveleva, A., Han, X., Spencer, B., Sapchenko, S., Tuna, F., Mcinnes, E., Ming, L., Yang, S. & Schroder, M., 1 Sep 2019, (Accepted/In press) In : Inorganic Chemistry.

    Research output: Contribution to journalArticle

  3. Published

    The Sensitivity of Magnetic Anisotropy in the Solid State for Lanthanide Complexes with Small Crystal Field Splitting

    Vonci, M., Mason, K., Neil, E., Yufit, D. S., Mcinnes, E., Parker, D. & Chilton, N., 6 May 2019, In : Inorganic Chemistry.

    Research output: Contribution to journalArticle

  4. Published

    Close encounters of the weak kind: Investigations of electron-electron interactions between dissimilar spins in hybrid rotaxanes

    Lockyer, S. J., Fielding, A. J., Whitehead, G. F. S., Timco, G. A., Winpenny, R. E. P. & Mcinnes, E. J. L., 2019, In : Journal of the American Chemical Society.

    Research output: Contribution to journalArticle

  5. Published

    Electronic Structures of Bent Lanthanide(III) Complexes with Two N-Donor Ligands

    Nicholas, H., Vonci, M., Goodwin, C. A. P., Loo, S. W., Murphy, S., Cassim, D., Winpenny, R. E. P., Mcinnes, E. J. L., Chilton, N. F. & Mills, D. P., 2019, In : Chemical Science.

    Research output: Contribution to journalArticle

  6. Published

    Periodic trends and hidden dynamics of magnetic properties in three series of triazacyclononane lanthanide complexes

    Parker, D., Suturina, E., Mason, K., Botta, M., Carniato, F., Kuprov, I., Chilton, N. F., Vonci, M. & Mcinnes, E. J. L., 2019, In : Dalton Transactions.

    Research output: Contribution to journalArticle

  7. Published

    Rigidification of a macrocyclic tris-catecholate scaffold leads to electronic localisation of its mixed valent redox product

    Greatorex, S., Vincent, K. B., Baldansuren, A., McInnes, E. J. L., Patmore, N. J., Sproules, S. & Halcrow, M. A., 2019, In : Chemical Communications. 55, 16, p. 2281-2284 4 p.

    Research output: Contribution to journalArticle

  8. Published

    Studies of Hysteresis and Quantum Tunnelling of the Magnetisation in Dysprosium(III) Single Molecule Magnets

    Ortu, F., Reta, D., Ding, Y., Goodwin, C. A. P., Gregson, M., Mcinnes, E. J. L., Winpenny, R. E. P., Zheng, Y., Liddle, S., Mills, D. P. & Chilton, N. F., 2019, In : Dalton Transactions.

    Research output: Contribution to journalArticle

  9. Published

    Thorium- and Uranium-Azide Reductions: A Transient Dithorium-Nitride Versus Isolable Diuranium-Nitrides

    Du, J., King, D. M., Chatelain, L., Lu, E., Tuna, F., Mcinnes, E. J. L., Wooles, A., Laurent, M. & Liddle, S., 2019, In : Chemical Science.

    Research output: Contribution to journalArticle

  10. 2018
  11. Published

    Hybrid organic-inorganic rotaxanes, including a hetero-hybrid [3]rotaxane featuring two distinct heterometallic rings and a molecular shuttle

    Timco, G., Fernandez Mato, A., Kostopoulos, A., Charlton, J. F., Lockyer, S., Hailes, T. R., Adams, R., Mcinnes, E., Tuna, F., Vitorica-Yrezabal, I., Whitehead, G. & Winpenny, R., 20 Aug 2018, In : Angewandte Chemie - International Edition. 57, 34, p. 10919-10922 3 p.

    Research output: Contribution to journalArticle

  12. Published

    Exquisite sensitivity of the ligand field to solvation and donor polarisability in coordinatively saturated lanthanide complexes

    Mason, K., Harnden, A. C., Patrick, C. W., Poh, A. W. J., Batsanov, A. S., Suturina, E. A., Vonci, M., McInnes, E. J. L., Chilton, N. F. & Parker, D., 26 Jul 2018, In : Chemical communications (Cambridge, England). 54, 61, p. 8486-8489 4 p.

    Research output: Contribution to journalArticle

  13. Published

    Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine- Titanium Complex

    Doyle, L., Wooles, A., Jenkins, L. C., Tuna, F., Mcinnes, E. & Liddle, S., 15 May 2018, In : Angewandte Chemie - International Edition. 57, 21, p. 6314-6318 4 p.

    Research output: Contribution to journalArticle

  14. Published

    Modular [(Fe8M6II)-M-III](&ITn&IT+)(M-II = Pd, Co, Ni, Cu) Coordination Cages

    Sanz, S., O'Connor, H. M., Comar, P., Baldansuren, A., Pitak, M. B., Coles, S. J., Weihe, H., Chilton, N. F., McInnes, E. J. L., Lusby, P. J., Piligkos, S. & Brechin, E. K., 2 Apr 2018, In : Inorganic Chemistry. 57, 7, p. 3500-3506

    Research output: Contribution to journalArticle

  15. Published

    Actinide-Transition Metal Bonding in Heterobimetallic Uranium- and Thorium-Molybdenum Paddlewheel Complexes

    Ayres, A., Zegke, M., Ostrowski, J., Tuna, F., Mcinnes, E. J. L., Wooles, A. & Liddle, S., 2018, In : Chemical Communications.

    Research output: Contribution to journalArticle

  16. Published

    Cages on a plane: a structural matrix for molecular ‘sheets'

    Fraser, H. W. L., Nichol, G. S., Baldansuren, A., McInnes, E. J. L. & Brechin, E. K., 2018, In : Dalton Transactions. 47, 43, p. 15530-15537 8 p.

    Research output: Contribution to journalArticle

  17. Published

    Exploring Synthetic Routes to Heteroleptic UIII, UIV and ThIV Bulky Bis(silyl)amide Complexes

    Goodwin, C., Tuna, F., Mcinnes, E. & Mills, D., 2018, In : European Journal of Inorganic Chemistry. 20-21

    Research output: Contribution to journalArticle

  18. Published

    Measurement of magnetic exchange in asymmetric lanthanide dimetallics: towards a transferable theoretical framework

    Giansiracusa, M., Moreno Pineda, E., Hussain, R., Marx, R., Prada, M. M., Neugebauer, P., Al-Badran, S., Collison, D., Tuna, F., Slageren, J. V., Carretta, S., Guidi, T., Mcinnes, E., Winpenny, R. & Chilton, N., 2018, In : American Chemical Society. Journal .

    Research output: Contribution to journalArticle

  19. Published

    Reversible adsorption of nitrogen dioxide within a robust porous metal-organic framework

    Han, X., Godfrey, H. G. W., Briggs, L., Davies, A. J., Cheng, Y., Daemen, L. L., Sheveleva, A. M., Tuna, F., Mcinnes, E. J. L., Sun, J., Drathen, C., George, M. W., Ramirez-Cuesta, A. J., Thomas, K. M., Yang, S. & Schroder, M., 2018, In : Nature Materials.

    Research output: Contribution to journalArticle

  20. Published

    Uranium(III)-Carbon Multiple Bonding Supported by Arene δ-Bonding in Mixed-Valence Hexauranium Nanometre-Scale Rings

    Wooles, A., Mills, D., Tuna, F., Mcinnes, E., Law, G., Fuller, A., Kremer, F., Ridgway, M., Lewis, W., Gagliardi, L., Vlaisavljevich, B. & Liddle, S., 2018, In : Nature Communications. 9, 2097.

    Research output: Contribution to journalArticle

  21. 2017
  22. Published

    Complexes of uranium and thorium with multiple bonds to tetryl and pnictide centers

    Liddle, S., Seed, J., Gregson, M., Wooles, A., Tuna, F. & McInnes, E., 2 Apr 2017, In : ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 253

    Research output: Contribution to journalMeeting Abstract

  23. Published

    Thorium redox chemistry and a new way to measure actinide covalency by pulsed EPR spectroscopy

    Mills, D., McInnes, E., Tuna, F., Kerridge, A., Maron, L., Formanuik, A., Ariciu, A-M., Ortu, F., Liu, J., Beekmeyer, R. & Castro, L., 2 Apr 2017, In : ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY. 253

    Research output: Contribution to journalMeeting Abstract

  24. Published

    [M2 IIIM3 II]n+ trigonal bipyramidal cages based on diamagnetic and paramagnetic metalloligands

    Sanz, S., O'Connor, H. M., Martí-Centelles, V., Comar, P., Pitak, M. B., Coles, S. J., Lorusso, G., Palacios, E., Evangelisti, M., Baldansuren, A., Chilton, N. F., Weihe, H., McInnes, E. J. L., Lusby, P. J., Piligkos, S. & Brechin, E. K., 2017, In : Chemical Science. 8, 8, p. 5526-5535 10 p.

    Research output: Contribution to journalArticle

  25. Published

    Actinide covalency measured by pulsed electron paramagnetic resonance spectroscopy

    Formanuik, A., Ariciu, A-M., Ortu, F., Beekmeyer, R., Kerridge, A., Tuna, F., Mcinnes, E. & Mills, D., 2017, In : Nature Chemistry. 9

    Research output: Contribution to journalArticle

  26. Published

    Evidence for Single Metal Two Electron Oxidative Addition and Reductive Elimination at Uranium

    Gardner, B. M., Kefalidis, C. E., Lu, E., Patel, D., Mcinnes, E., Tuna, F., Wooles, A., Maron, L. & Liddle, S., 2017, In : Nature Communications. 8, 1898.

    Research output: Contribution to journalArticle

  27. Published

    Modulating Supramolecular Binding of Carbon Dioxide in a Redox-Active Porous Metal-Organic Framework

    Lu, Z., Godfrey, H., Da Silva, I., Cheng, Y., Savage, M., Tuna, F., Mcinnes, E., Teat, S. J., Gagnon, K. J., Frogley, M. D., Manuel, P., Rudić, S., J. Ramirez-Cuesta, A., Easun, T. L., Yang, S. & Schroder, M., 2017, In : Nature Communications. 8, 14212.

    Research output: Contribution to journalArticle

  28. Published

    Rare Earth- and Uranium-Mesoionic Carbenes: A New Class of f-Block Carbene Complex Derived from an N-Heterocyclic Olefin

    Liddle, S., Seed, J., Gregson, M., Tuna, F., Chilton, N., Wooles, A. & Mcinnes, E., 2017, In : Angewandte Chemie - International Edition.

    Research output: Contribution to journalArticle

  29. Published

    Rationalisation of anomalous pseudo-contact shifts and their solvent dependence in a series of C3-symmetric lanthanide complexes

    Vonci, M., Mason, K., Suturina, E. A., Frawley, A. T., Worswick, S. G., Kuprov, I., Parker, D., Mcinnes, E. & Chilton, N., 2017, In : American Chemical Society. Journal .

    Research output: Contribution to journalArticle

  30. Published

    Terminal Uranium(V/VI)-Nitride Activation of Carbon Dioxide and Disulfide: Factors Governing Diverse and Well-Defined Cleavage and Redox Reactions

    Cleaves, P., Kefalidis, C. E., Gardner, B., Tuna, F., Mcinnes, E., Lewis, W., Maron, L. & Liddle, S., 2017, In : Chemistry: A European Journal. 23, 12

    Research output: Contribution to journalArticle

  31. Published

    The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes

    Gregson, M., Lu, E., Mills, D., Tuna, F., Mcinnes, E., Hennig, C., Scheinost, A. C., McMaster, J., Lewis, W., Blake, A. J., Kerridge, A. & Liddle, S., 2017, In : Nature Communications. 8, 14137.

    Research output: Contribution to journalArticle

  32. 2016
  33. Published

    Switchable Interaction in Molecular Double Qubits

    Ferrando-Soria, J., Magee, S. A., Chiesa, A., Carretta, S., Santini, P., Vitorica-Yrezabal, I. J., Tuna, F., Whitehead, G. F. S., Sproules, S., Lancaster, K. M., Barra, A. L., Timco, G. A., McInnes, E. J. L. & Winpenny, R. E. P., 10 Nov 2016, In : Chem. 1, 5, p. 727-752 26 p.

    Research output: Contribution to journalArticle

  34. Published

    A Facile Synthetic Route to a Family of MnIII Monomers and Their Structural, Magnetic and Spectroscopic Studies

    Houton, E., Kelly, B., Sanz, S., Mcinnes, E. J. L., Collison, D., Brechin, E. K., Barra, A., Ryder, A. G. & Jones, L. F., 1 Nov 2016, In : European Journal of Inorganic Chemistry. 2016, 32, p. 5123-5131

    Research output: Contribution to journalArticle

  35. Published

    Observation of the Influence of Dipolar and Spin Frustration Effects on the Magnetocaloric Properties of a Trigonal Prismatic {Gd7} Molecular Nanomagnet

    Moreno Pineda, E., Lorusso, G., Zangana, K., Palacios, E., Schnack, J., Evangelisti, M., Winpenny, R. & Mcinnes, E., 1 Aug 2016, In : Chemical Science. 7, 8, p. 4891-4895 5 p.

    Research output: Contribution to journalArticle

  36. Published

    A Monometallic Lanthanide Bis(methanediide) Single Molecule Magnet with a Large Energy Barrier and Complex Spin Relaxation Behaviour

    Gregson, M., Chilton, N. F., Ariciu, A-M., Tuna, F., Crowe, I., Lewis, W., Blake, A. J., Collison, D., Mcinnes, E., Winpenny, R. & Liddle, S. T., 1 Jul 2016, In : Chemical Science. 7, p. 155-165 10 p.

    Research output: Contribution to journalArticle

  37. Published

    A modular design of molecular qubits to implement universal quantum gates

    Ferrando-Soria, J., Pineda, E. M., Chiesa, A., Fernandez, A., Magee, S. A., Carretta, S., Santini, P., Yrezabal, I. J. V., Tuna, F., Timco, G. A., Mcinnes, E. J. L. & Winpenny, R. E. P., 25 Apr 2016, In : Nature Communications.

    Research output: Contribution to journalArticle

  38. Published

    Emergence of Comparable Covalency in Isostructural Cerium(IV)- and Uranium(IV)-Carbon Multiple Bonds

    Gregson, M., Lu, E., Liddle, S., Tuna, F., Mcinnes, E. J. L., Hennig, C., Scheinost, A. C., McMaster, J., Lewis, W., Blake, A. J. & Kerridge, A., 4 Feb 2016, In : Chemical Science. 7, 5, p. 3286 3297 p.

    Research output: Contribution to journalArticle

  39. Published

    Studies of a Large Odd-Numbered Odd-Electron Metal Ring: Inelastic Neutron Scattering and Muon Spin Relaxation Spectroscopy of Cr8Mn

    Baker, M., Lancaster, T., Chiesa, A., Amoretti, G., Baker, P. J., Barker, C., Blundell, S. J., Carretta, S., Collison, D., Guedel, H. U., Guidi, T., Mcinnes, E., Moeller, J. S., Mutka, H., Ollivier, J., Pratt, F. L., Santini, P., Tuna, F., Tregenna-Piggott, P. L., Vitorica-Yrezabal, I. & 2 othersTimco, G. & Winpenny, R., Jan 2016, In : Chemistry: A European Journal. 22, 5, p. 1779–1788

    Research output: Contribution to journalArticle

  40. Published

    EPR interactions-coupled spins

    McInnes, E. J. L. & Collison, D., 2016, In : eMagRes. 5, 3, p. 1445-1458 14 p.

    Research output: Contribution to journalArticle

  41. Published

    Heterodimers of Heterometallic Rings

    Timco, G., Mcinnes, E., Pritchard, R., Tuna, F. & Winpenny et al, R., 2016, In : Dalton Transactions. 45, p. 16610-16615 6 p.

    Research output: Contribution to journalArticle

  42. Published

    Inter- versus Intramolecular Structural Manipulation of a Dichromium(II) Pacman Complex through Pressure Variation

    Stevens, C. J., Prescimone, A., Tuna, F., Mcinnes, E. J. L., Parsons, S., Morrison, C. A., Arnold, P. L. & Love, J. B., 2016, In : Inorganic Chemistry: including bioinorganic chemistry . p. 214-220 6 p.

    Research output: Contribution to journalArticle

  43. Published

    Molecular and Electronic Structure of Terminal and Alkali Metal-Capped Uranium(V)-Nitride Complexes

    King, D., Cleaves, P., Wooles, A., Gardner, B., Chilton, N., Tuna, F., Lewis, W., Mcinnes, E. & Liddle, S., 2016, In : Nature Communications. 7, 13773.

    Research output: Contribution to journalArticle

  44. 2015
  45. Published

    Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex

    Gardner, B. M., Balazs, G., Scheer, M., Wooles, A. J., Tuna, F., Mcinnes, E. J. L., McMaster, J., Lewis, W., Blake, A. J. & Liddle, S. T., 28 Oct 2015, In : Angewandte Chemie (International Edition). 54, p. 15250-15254 4 p.

    Research output: Contribution to journalArticle

  46. Published

    Engineering coherent interactions in molecular nanomagnet dimers

    Ardavan, A., Bowen, A. M., Fernandez, A., Fielding, A. J., Kaminski, D., Moro, F., Muryn, C. A., Wise, M. D., Ruggi, A., Mcinnes, E. J. L., Severin, K., Timco, G. A., Timmel, C. R., Tuna, F., Whitehead, G. F. S. & Winpenny, R. E. P., Oct 2015, In : N P J Quantum Information. 15012.

    Research output: Contribution to journalArticle

  47. Published

    Spectroscopic and Crystal Field Consequences of Fluoride Binding by [Yb.DTMA]3+ in Aqueous Solution

    Blackburn, O. A., Chilton, N. F., Keller, K., Tait, C. E., Myers, W. K., McInnes, E. J. L., Kenwright, A. M., Beer, P. D., Timmel, C. R. & Faulkner, S., Sep 2015, In : Angewandte Chemie International Edition. 54, 37, p. 10783-10786 4 p.

    Research output: Contribution to journalArticle

  48. Published

    Influencing the Properties of Dysprosium Single-Molecule Magnets with Phosphorus Donor Ligands

    Pugh, T., Tuna, F., Ungur, L., Collison, D., McInnes, E. J. L., Chibotaru, L. F. & Layfield, R. A., Jul 2015, In : Nature Communications. 6, NCOMMS-15-02344B.

    Research output: Contribution to journalArticle

  49. Published

    A Hybrid Organic-Inorganic Molecular Daisy Chain

    Mcinnes, E., Fernandez, A., Pineda, E. M., Ferrando-Soria, J., Mcinnes, E., Timco, G. & Winpenny, R., 15 Jun 2015, In : Chemical Communications. 51, 55, p. 11126-11129 4 p.

    Research output: Contribution to journalArticle

  50. Published

    Triamidoamine uranium(IV)–arsenic complexes containing one-, two- and threefold U–As bonding interactions

    Gardner, B., Balazs, G., Scheer, M., Tuna, F., Mcinnes, E., McMaster, J., Lewis, W., Blake, A. J. & Liddle, S., 15 Jun 2015, In : Nature Chemistry. 54, 7, p. 582-590

    Research output: Contribution to journalArticle

  51. Published

    Systematic study of a family of butterfly-like {M2Ln2} molecular magnets (M = MgII, MnIII, CoII, NiII and CuII; Ln = YIII, GdIII, TbIII, DyIII, HoIII and ErIII)

    Pineda, E. M., Chilton, N., Tuna, F., Winpenny, R. E. P. & Mcinnes, E. J. L., 27 May 2015, In : Inorganic Chemistry: including bioinorganic chemistry .

    Research output: Contribution to journalArticle

  52. Published

    An Inverted-​Sandwich Diuranium μ-​η5:η5-​Cyclo-​P5 Complex Supported by U-​P5 δ-​Bonding

    Gardner, B., Tuna, F., Mcinnes, E., McMaster, J., Lewis, W., Blake, A. J. & Liddle, S., 2015, In : Angewandte Chemie (International Edition). 54, 24, p. 7068-7072 4 p.

    Research output: Contribution to journalArticle

  53. Published

    Electronic Structure of a Mixed-Metal Fluoride-Centered Triangle Complex: A Potential Qubit Component

    Walsh, J. P. S., Meadows, S. B., Ghirri, A., Moro, F., Jennings, M., Smith, W. F., Graham, D. M., Kihara, T., Nojiri, H., Vitorica-Yrezabal, I. J., Timco, G. A., Collison, D., Mcinnes, E. J. L. & Winpenny, R. E. P., 2015, In : Inorganic Chemistry. 54, 24, p. 12019-12026 7 p.

    Research output: Contribution to journalArticle

  54. Published

    Platinum(II) Complexes of Mixed-Valent Radicals Derived from Cyclotricatechylene, a Macrocyclic Tris-Dioxolene

    Loughrey, J. J., Patmore, N. J., Baldansuren, A., Fielding, A. J., Mcinnes, E. J. L., Hardie, M., Sproules, S. & Halcrow, M., 2015, In : Chemical Science. 6, p. 6935-6948 13 p.

    Research output: Contribution to journalArticle

  55. 2014
  56. Published

    Direct measurement of dysprosium(III)˙˙˙dysprosium(III) interactions in a single-molecule magnet

    Moreno Pineda, E., Chilton, N. F., Marx, R., Dorfel, M., Sells, D. O., Neugebauer, P., Jiang, S-D., Collison, D., van Slageren, J., Mcinnes, E. & Winpenny, R. EP., Oct 2014, In : Nature Communications. 5, p. 5243-5243 1 p.

    Research output: Contribution to journalArticle

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