Visible-Light-Mediated Reactions of Electrophilic Radicals with Vi-nyl and Allyl Trifluoroborates

Research output: Contribution to journalArticle

  • Authors:
  • Daniel Fernández Reina
  • Alessandro Ruffoni
  • Yasair S.S Al-Faiyz
  • Nadeem Sheikh
  • Daniele Leonori

Abstract

Visible-light photoredox catalysis enables the vinylation and allylation of electrophilic radicals with readily available potassium trifluoroborate reagents. The processes show good functional group compatibility, and mechanistic and computational studies have elucidated some of the aspects associated with the key radical addition step.

Bibliographical metadata

Original languageEnglish
Pages (from-to)4126-4130
Number of pages5
JournalACS Catalysis
Volume2017
Issue number6
Early online date15 May 2017
DOIs
Publication statusPublished - 2017