Conventional chemical oxidation routes for the production of graphene oxide (GO), such as the Hummers method, suffer from environmental and safety issues due to their use of hazardous and explosive chemicals. These issues are addressed by electrochemical oxidation methods but such approaches typically have a low yield due to inhomogeneous oxidation. Herein we report a two-step electrochemical intercalation and oxidation approach to produce GO on a large laboratory scale (ten’s of grams) comprising: (1) forming a stage 1 graphite intercalation compound (GIC) in concentrated sulfuric acid; (2) oxidizing and exfoliating the stage 1 GIC in an aqueous solution of 0.1 M ammonium sulfate. This two-step approach leads to GO with a high yield (>70 wt.%), good quality (>90%, monolayer), and reasonable oxygen content (17.7 at.%). Moreover, the as-produced GO can be subsequently deeply reduced (3.2 at.% oxygen; C/O ratio 30.2) to yield highly conductive (54,600 S m−1) reduced GO. Electrochemical capacitors based on the reduced GO showed an ultra-high rate capability of up to 10 V s−1 due to this high conductivity.