The electro-oxidation of dimethylamine borane: Part 2, in situ FTIR on single-crystal gold electrodesCitation formats

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The electro-oxidation of dimethylamine borane: Part 2, in situ FTIR on single-crystal gold electrodes. / Plana, Daniela; Rodriguez, Paramaconi; Koper, Marc T M; Dryfe, Robert A W.

In: Electrochimica Acta, Vol. 56, No. 22, 01.09.2011, p. 7637-7643.

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Plana, Daniela ; Rodriguez, Paramaconi ; Koper, Marc T M ; Dryfe, Robert A W. / The electro-oxidation of dimethylamine borane: Part 2, in situ FTIR on single-crystal gold electrodes. In: Electrochimica Acta. 2011 ; Vol. 56, No. 22. pp. 7637-7643.

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@article{473685d26b8c491c98b7c0f902eb241d,
title = "The electro-oxidation of dimethylamine borane: Part 2, in situ FTIR on single-crystal gold electrodes",
abstract = "Dimethylamine borane (DMAB) electro-oxidation in alkaline media was studied using static and rotating gold single-crystal electrodes in the hanging-meniscus configuration. DMAB oxidation showed a strong sensitivity towards surface structure on gold electrodes. In situ Fourier transform infrared (FTIR) spectroscopy revealed that the potential-dependent cleavage of the B-N bond is one of the initial steps of the oxidation process. FTIR also showed that dimethylamine is oxidised in the potential range of gold oxide formation. {\circledC} 2011 Elsevier Ltd. All rights reserved.",
keywords = "DMAB oxidation, Electroless deposition, FTIR, Reducing agent, Single-crystal gold electrodes",
author = "Daniela Plana and Paramaconi Rodriguez and Koper, {Marc T M} and Dryfe, {Robert A W}",
year = "2011",
month = "9",
day = "1",
doi = "10.1016/j.electacta.2011.06.072",
language = "English",
volume = "56",
pages = "7637--7643",
journal = "Electrochim Acta",
issn = "0013-4686",
publisher = "Elsevier BV",
number = "22",

}

RIS

TY - JOUR

T1 - The electro-oxidation of dimethylamine borane: Part 2, in situ FTIR on single-crystal gold electrodes

AU - Plana, Daniela

AU - Rodriguez, Paramaconi

AU - Koper, Marc T M

AU - Dryfe, Robert A W

PY - 2011/9/1

Y1 - 2011/9/1

N2 - Dimethylamine borane (DMAB) electro-oxidation in alkaline media was studied using static and rotating gold single-crystal electrodes in the hanging-meniscus configuration. DMAB oxidation showed a strong sensitivity towards surface structure on gold electrodes. In situ Fourier transform infrared (FTIR) spectroscopy revealed that the potential-dependent cleavage of the B-N bond is one of the initial steps of the oxidation process. FTIR also showed that dimethylamine is oxidised in the potential range of gold oxide formation. © 2011 Elsevier Ltd. All rights reserved.

AB - Dimethylamine borane (DMAB) electro-oxidation in alkaline media was studied using static and rotating gold single-crystal electrodes in the hanging-meniscus configuration. DMAB oxidation showed a strong sensitivity towards surface structure on gold electrodes. In situ Fourier transform infrared (FTIR) spectroscopy revealed that the potential-dependent cleavage of the B-N bond is one of the initial steps of the oxidation process. FTIR also showed that dimethylamine is oxidised in the potential range of gold oxide formation. © 2011 Elsevier Ltd. All rights reserved.

KW - DMAB oxidation

KW - Electroless deposition

KW - FTIR

KW - Reducing agent

KW - Single-crystal gold electrodes

U2 - 10.1016/j.electacta.2011.06.072

DO - 10.1016/j.electacta.2011.06.072

M3 - Article

VL - 56

SP - 7637

EP - 7643

JO - Electrochim Acta

JF - Electrochim Acta

SN - 0013-4686

IS - 22

ER -