The Cross-Dehydrogenative-Coupling of Alkoxybenzenes with Toluenes: Copper(II) Halide Mediated Tandem Halo/Benzylation of ArenesCitation formats

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The Cross-Dehydrogenative-Coupling of Alkoxybenzenes with Toluenes: Copper(II) Halide Mediated Tandem Halo/Benzylation of Arenes. / Storr, Thomas; Teskey, Christopher; Greaney, Michael.

In: Chem.Eur. J., Vol. 22, No. 50, 12.12.2016, p. 18169-18178.

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Storr, Thomas ; Teskey, Christopher ; Greaney, Michael. / The Cross-Dehydrogenative-Coupling of Alkoxybenzenes with Toluenes: Copper(II) Halide Mediated Tandem Halo/Benzylation of Arenes. In: Chem.Eur. J. 2016 ; Vol. 22, No. 50. pp. 18169-18178.

Bibtex

@article{55e7e0f255764d87bf984c40613670c4,
title = "The Cross-Dehydrogenative-Coupling of Alkoxybenzenes with Toluenes: Copper(II) Halide Mediated Tandem Halo/Benzylation of Arenes",
abstract = "A cross-dehydrogenative-coupling of alkoxybenzenes and toluenes with concomitant halogenation is reported. Conditions employed were the use of stoichiometric copper halide salts and dialkylperoxides to afford a range of bromoalkoxydi- and triarylmethanes. Preliminary mechanistic studies suggest that the in situ production of haloarenes (or dihaloarenes) followed by a copper mediated coupling of a benzylic radical is operational.",
author = "Thomas Storr and Christopher Teskey and Michael Greaney",
year = "2016",
month = dec,
day = "12",
doi = "10.1002/chem.201603783",
language = "English",
volume = "22",
pages = "18169--18178",
journal = "Chemistry: A European Journal ",
issn = "0947-6539",
publisher = "John Wiley & Sons Ltd",
number = "50",

}

RIS

TY - JOUR

T1 - The Cross-Dehydrogenative-Coupling of Alkoxybenzenes with Toluenes: Copper(II) Halide Mediated Tandem Halo/Benzylation of Arenes

AU - Storr, Thomas

AU - Teskey, Christopher

AU - Greaney, Michael

PY - 2016/12/12

Y1 - 2016/12/12

N2 - A cross-dehydrogenative-coupling of alkoxybenzenes and toluenes with concomitant halogenation is reported. Conditions employed were the use of stoichiometric copper halide salts and dialkylperoxides to afford a range of bromoalkoxydi- and triarylmethanes. Preliminary mechanistic studies suggest that the in situ production of haloarenes (or dihaloarenes) followed by a copper mediated coupling of a benzylic radical is operational.

AB - A cross-dehydrogenative-coupling of alkoxybenzenes and toluenes with concomitant halogenation is reported. Conditions employed were the use of stoichiometric copper halide salts and dialkylperoxides to afford a range of bromoalkoxydi- and triarylmethanes. Preliminary mechanistic studies suggest that the in situ production of haloarenes (or dihaloarenes) followed by a copper mediated coupling of a benzylic radical is operational.

U2 - 10.1002/chem.201603783

DO - 10.1002/chem.201603783

M3 - Article

VL - 22

SP - 18169

EP - 18178

JO - Chemistry: A European Journal

JF - Chemistry: A European Journal

SN - 0947-6539

IS - 50

ER -