The Assembly of “S3N” – Ligands Decorated with an Azo-Dye as Potential Sensors for Heavy Metal Ions

Research output: Contribution to journalArticle

  • External authors:
  • Omer Rasheed
  • Christopher Muryn
  • James Raftery
  • Inigo Vitorica-Yrezabal

Abstract

An “S3N-ligand azo-dye” conjugate has been synthesised with a view to the development of a sensor for heavy metal ions. Complexation of this system with Ag(I), Hg(II) and Cu(II) salts has been investigated and an X-ray structure obtained for a Hg(II) complex. Complexation of the conjugated dye to these metals results in a bathochromic shift in the absorption maximum of the azo dye, an effect which is most pronounced for Cu(II).

Bibliographical metadata

Original languageEnglish
Pages (from-to)5229-5239
Number of pages11
JournalDalton Transactions
Volume2017
Issue number16
Early online date15 Mar 2017
DOIs
StatePublished - 2017