Synthesis, structural and magnetic characterisation of iron(II/III), cobalt(II) and copper(II) cluster complexes of the polytopic ligand: N-(2-pyridyl)-3-carboxypropanamide

Research output: Contribution to journalArticle

  • External authors:
  • Mark E Russell
  • Chris S Hawes
  • Alan Ferguson
  • Matthew I J Polson
  • Boujemaa Moubaraki
  • Keith S Murray
  • Paul E Kruger

Abstract

Herein we describe the synthesis, structural and magnetic characterisation of three transition metal cluster complexes that feature the polytopic ligand N-(2-pyridyl)-3-carboxypropanamide (H2L): [Fe3IIIFe2II(HL)6(O)(H2O)3][ClO4]5??3MeCN??4H2O, 1, [Co8(HL)8(O)(OH)4(MeOH)3(H2O)]-[ClO4]3??5MeOH??2H2O, 2, and [Cu6(L

Bibliographical metadata

Original languageEnglish
Pages (from-to)13576-13583
Number of pages8
JournalDalton Transactions
Volume42
Issue number37
DOIs
Publication statusPublished - Sep 2013