Stepwise Observation and Quantification and Mixed Matrix Membrane Separation of CO2 within a Hydroxy-Decorated Porous Host

Research output: Contribution to journalArticle

  • External authors:
  • Christopher Morris
  • Nicholas Jacques
  • Harry Godfrey
  • Tamoghna Mitra
  • Detlev Fritsch
  • Zhenzhong Lu
  • Claire A. Murray
  • Jonathan Potter
  • Tom M. Cobb
  • Fajin Yuan
  • Chiu Tang


The identification of preferred binding domains within a host structure provides important insights into the function of materials. State-of-the-art reports mostly focus on crystallographic studies of empty and single component guest-loaded host structures to determine the location of guests. However, measurements of material properties (e.g., adsorption and breakthrough of substrates) are usually performed for a wide range of pressure (guest coverage) and/or using multi-component gas mixtures. Here we report the development of a multifunctional gas dosing system for use in X-ray powder diffraction studies on Beamline I11 at Diamond Light Source. This facility is fully automated and enables in situ crystallographic studies of host structures under (i) unlimited target gas loadings and (ii) loading of multi-component gas mixtures. A proof-of-concept study was conducted on a hydroxyl-decorated porous material MFM-300(VIII) under (i) five different CO2 pressures covering the isotherm range and (ii) the loading of equimolar mixtures of CO2/N2. The study has successfully captured the structural dynamics underpinning CO2 uptake as a function of surface coverage. Moreover, MFM-300(VIII) was incorporated in a mixed matrix membrane (MMM) with PIM-1 in order to evaluate the CO2/N2 separation potential of this material. Gas permeation measurements on the MMM show a great improvement over the bare PIM-1 polymer for CO2/N2 separation based on the ideal selectivity.

Bibliographical metadata

Original languageEnglish
Pages (from-to)3239-3248
Number of pages10
JournalChemical Science
Issue number8
Early online date27 Feb 2017
StatePublished - 2017