Spectroelectrochemical properties of a Ru(ii) complex with a thiazolo[5,4-d]thiazole triarylamine ligand

Research output: Contribution to journalArticle

  • Authors:
  • Carol Hua
  • Felix J. Rizzuto
  • Xuan Zhang
  • Floriana Tuna
  • David Collison
  • And 1 others
  • External authors:
  • Deanna M. D'Alessandro

Abstract

A new bis-chelating ligand containing a triarylamine electron donor core fused with a thiazolo-thiazole electron acceptor, N,N′-(thiazolo[5,4-d]thiazole-2,5-diylbis(4,1-phenylene))bis(N-(pyridin-2-yl)pyridin-2-amine) (1) has been synthesised. This non-innocent ligand exhibits interesting electronic and spectral properties that can be tuned as a function of its redox state. In particular, modulation of the electronic state can be used to turn the fluorescence on and off. A dinuclear Ru(ii) terpyridine complex, [Ru2(tpy)2Cl2(1)](PF6)2 (2) was subsequently synthesised and the properties of each of the accessible redox states explored using in situ spectroelectrochemical techniques.

Bibliographical metadata

Original languageEnglish
Pages (from-to)108-114
Number of pages7
JournalNew Journal of Chemistry
Volume41
Issue number1
Early online date16 Nov 2016
DOIs
StatePublished - 2017