Slow magnetic relaxation in a {EuCu5} metallacrownCitation formats

  • External authors:
  • Jin Wang
  • Ze-yu Ruan
  • Quan-wen Li
  • Yan-cong Chen
  • Guo-zhang Huang
  • Jun-liang Liu
  • Zhen-xing Wang
  • Ming-liang Tong

Standard

Slow magnetic relaxation in a {EuCu5} metallacrown. / Wang, Jin; Ruan, Ze-yu; Li, Quan-wen; Chen, Yan-cong; Huang, Guo-zhang; Liu, Jun-liang; Reta, Daniel; Chilton, Nicholas F.; Wang, Zhen-xing; Tong, Ming-liang.

In: Dalton Transactions, Vol. 48, No. 5, 2019, p. 1686-1692.

Research output: Contribution to journal › Article

Harvard

Wang, J, Ruan, Z, Li, Q, Chen, Y, Huang, G, Liu, J, Reta, D, Chilton, NF, Wang, Z & Tong, M 2019, 'Slow magnetic relaxation in a {EuCu5} metallacrown', Dalton Transactions, vol. 48, no. 5, pp. 1686-1692. https://doi.org/10.1039/C8DT04814B

APA

Wang, J., Ruan, Z., Li, Q., Chen, Y., Huang, G., Liu, J., ... Tong, M. (2019). Slow magnetic relaxation in a {EuCu5} metallacrown. Dalton Transactions, 48(5), 1686-1692. https://doi.org/10.1039/C8DT04814B

Vancouver

Wang J, Ruan Z, Li Q, Chen Y, Huang G, Liu J et al. Slow magnetic relaxation in a {EuCu5} metallacrown. Dalton Transactions. 2019;48(5):1686-1692. https://doi.org/10.1039/C8DT04814B

Author

Wang, Jin ; Ruan, Ze-yu ; Li, Quan-wen ; Chen, Yan-cong ; Huang, Guo-zhang ; Liu, Jun-liang ; Reta, Daniel ; Chilton, Nicholas F. ; Wang, Zhen-xing ; Tong, Ming-liang. / Slow magnetic relaxation in a {EuCu5} metallacrown. In: Dalton Transactions. 2019 ; Vol. 48, No. 5. pp. 1686-1692.

Bibtex

@article{53063db61668441dac6690a67a27068f,
title = "Slow magnetic relaxation in a {EuCu5} metallacrown",
abstract = "A 3d–4f heterometallic metallacrown with formula of [EuCu5(quinha)5(sal)2(py)5]CF3SO3·py·3H2O (1) (H2quinha = quinaldichydroxamic acid; Hsal = salicylaldehyde) has been synthesized. This complex shows field-induced slow magnetic relaxation via a Raman-like process, where studies of the isostructural {LuCu5} (2) and {YCu5} (3) complexes show that the slow dynamics mainly arise from the {Cu5} S = 1/2 ground state rather than the EuIII ion. However, the EuIII ion enhances the relaxation rates of the {Cu5} unit which likely arises from second-order effects in the formally diamagnetic 7F0 ground state of EuIII.",
author = "Jin Wang and Ze-yu Ruan and Quan-wen Li and Yan-cong Chen and Guo-zhang Huang and Jun-liang Liu and Daniel Reta and Chilton, {Nicholas F.} and Zhen-xing Wang and Ming-liang Tong",
year = "2019",
doi = "10.1039/C8DT04814B",
language = "English",
volume = "48",
pages = "1686--1692",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "5",

}

RIS

TY - JOUR

T1 - Slow magnetic relaxation in a {EuCu5} metallacrown

AU - Wang, Jin

AU - Ruan, Ze-yu

AU - Li, Quan-wen

AU - Chen, Yan-cong

AU - Huang, Guo-zhang

AU - Liu, Jun-liang

AU - Reta, Daniel

AU - Chilton, Nicholas F.

AU - Wang, Zhen-xing

AU - Tong, Ming-liang

PY - 2019

Y1 - 2019

N2 - A 3d–4f heterometallic metallacrown with formula of [EuCu5(quinha)5(sal)2(py)5]CF3SO3·py·3H2O (1) (H2quinha = quinaldichydroxamic acid; Hsal = salicylaldehyde) has been synthesized. This complex shows field-induced slow magnetic relaxation via a Raman-like process, where studies of the isostructural {LuCu5} (2) and {YCu5} (3) complexes show that the slow dynamics mainly arise from the {Cu5} S = 1/2 ground state rather than the EuIII ion. However, the EuIII ion enhances the relaxation rates of the {Cu5} unit which likely arises from second-order effects in the formally diamagnetic 7F0 ground state of EuIII.

AB - A 3d–4f heterometallic metallacrown with formula of [EuCu5(quinha)5(sal)2(py)5]CF3SO3·py·3H2O (1) (H2quinha = quinaldichydroxamic acid; Hsal = salicylaldehyde) has been synthesized. This complex shows field-induced slow magnetic relaxation via a Raman-like process, where studies of the isostructural {LuCu5} (2) and {YCu5} (3) complexes show that the slow dynamics mainly arise from the {Cu5} S = 1/2 ground state rather than the EuIII ion. However, the EuIII ion enhances the relaxation rates of the {Cu5} unit which likely arises from second-order effects in the formally diamagnetic 7F0 ground state of EuIII.

U2 - 10.1039/C8DT04814B

DO - 10.1039/C8DT04814B

M3 - Article

VL - 48

SP - 1686

EP - 1692

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 5

ER -