Simultaneous Neutron Powder Diffraction and Microwave Characterisation at Elevated TemperaturesCitation formats

  • External authors:
  • Michael Barter
  • Gemma Smith
  • Martin Owen Jones
  • Adrian Porch

Standard

Simultaneous Neutron Powder Diffraction and Microwave Characterisation at Elevated Temperatures. / Barter, Michael; Smith, Gemma; Yang, Sihai; Schroder, Martin; Jones, Martin Owen; Porch, Adrian.

In: Physical Chemistry Chemical Physics, 08.10.2021.

Research output: Contribution to journalArticlepeer-review

Harvard

APA

Vancouver

Author

Barter, Michael ; Smith, Gemma ; Yang, Sihai ; Schroder, Martin ; Jones, Martin Owen ; Porch, Adrian. / Simultaneous Neutron Powder Diffraction and Microwave Characterisation at Elevated Temperatures. In: Physical Chemistry Chemical Physics. 2021.

Bibtex

@article{2e3d1df738f44ce4b035a9a653a6b219,
title = "Simultaneous Neutron Powder Diffraction and Microwave Characterisation at Elevated Temperatures",
abstract = "The use of simultaneous neutron powder diffraction (NPD) and microwave characterisation can provide more information than the use of either technique individually; for example, it enables the differentiation of physisorbed and metal-coordinated species. Many possible experiments using these combined techniques can benefit from the addition of a heat source for sample heating, such as real-time measurements of solvent removal, or chemical and catalytic reactions. This paper documents the design of equipment to conduct simultaneous NPD and 2.5 GHz microwave cavity resonance techniques at elevated temperatures and confirms the use of this equipment for successful desolvation of a metal–organic framework (MOF) sample at 150 °C. The high sensitivity of microwave characterisation of lossy and polar materials is demonstrated at levels much lower than those that can be detected using crystallographic techniques.",
author = "Michael Barter and Gemma Smith and Sihai Yang and Martin Schroder and Jones, {Martin Owen} and Adrian Porch",
year = "2021",
month = oct,
day = "8",
doi = "10.1039/D1CP03658K",
language = "English",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",

}

RIS

TY - JOUR

T1 - Simultaneous Neutron Powder Diffraction and Microwave Characterisation at Elevated Temperatures

AU - Barter, Michael

AU - Smith, Gemma

AU - Yang, Sihai

AU - Schroder, Martin

AU - Jones, Martin Owen

AU - Porch, Adrian

PY - 2021/10/8

Y1 - 2021/10/8

N2 - The use of simultaneous neutron powder diffraction (NPD) and microwave characterisation can provide more information than the use of either technique individually; for example, it enables the differentiation of physisorbed and metal-coordinated species. Many possible experiments using these combined techniques can benefit from the addition of a heat source for sample heating, such as real-time measurements of solvent removal, or chemical and catalytic reactions. This paper documents the design of equipment to conduct simultaneous NPD and 2.5 GHz microwave cavity resonance techniques at elevated temperatures and confirms the use of this equipment for successful desolvation of a metal–organic framework (MOF) sample at 150 °C. The high sensitivity of microwave characterisation of lossy and polar materials is demonstrated at levels much lower than those that can be detected using crystallographic techniques.

AB - The use of simultaneous neutron powder diffraction (NPD) and microwave characterisation can provide more information than the use of either technique individually; for example, it enables the differentiation of physisorbed and metal-coordinated species. Many possible experiments using these combined techniques can benefit from the addition of a heat source for sample heating, such as real-time measurements of solvent removal, or chemical and catalytic reactions. This paper documents the design of equipment to conduct simultaneous NPD and 2.5 GHz microwave cavity resonance techniques at elevated temperatures and confirms the use of this equipment for successful desolvation of a metal–organic framework (MOF) sample at 150 °C. The high sensitivity of microwave characterisation of lossy and polar materials is demonstrated at levels much lower than those that can be detected using crystallographic techniques.

U2 - 10.1039/D1CP03658K

DO - 10.1039/D1CP03658K

M3 - Article

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

ER -