Mechanistic observations on the unusual reactivity of dioxenone photosubstrates in the synthesis of ingenol

Research output: Contribution to journalArticle


The irradiation of allylically substituted dioxenone photosubstrates 6 and 21 lead to unexpected products, the formation of which can be explained by a series of transannular hydrogen atom abstractions.

Bibliographical metadata

Original languageEnglish
Pages (from-to)2150-2154
Number of pages4
Journal Synthesis: journal of synthetic organic chemistry
Issue number14
StatePublished - 2002