F-block N-heterocyclic carbene complexesCitation formats

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F-block N-heterocyclic carbene complexes. / Arnold, Plly L; Liddle, Stephen T.

In: Chemical Communications, No. 38, 08.2006, p. 3959-3971.

Research output: Contribution to journalArticle

Harvard

Arnold, PL & Liddle, ST 2006, 'F-block N-heterocyclic carbene complexes', Chemical Communications, no. 38, pp. 3959-3971. https://doi.org/10.1039/B606829D

APA

Arnold, P. L., & Liddle, S. T. (2006). F-block N-heterocyclic carbene complexes. Chemical Communications, (38), 3959-3971. https://doi.org/10.1039/B606829D

Vancouver

Arnold PL, Liddle ST. F-block N-heterocyclic carbene complexes. Chemical Communications. 2006 Aug;(38):3959-3971. https://doi.org/10.1039/B606829D

Author

Arnold, Plly L ; Liddle, Stephen T. / F-block N-heterocyclic carbene complexes. In: Chemical Communications. 2006 ; No. 38. pp. 3959-3971.

Bibtex

@article{0c1f2476c3c7414d9e72a4a94234e378,
title = "F-block N-heterocyclic carbene complexes",
abstract = "N-Heterocyclic carbenes (NHCs) can bind as two-electron σ-donor ligands to lanthanide and actinide metal cations. In this review we summarise how the incorporation of an anionic group (alkoxide or amido), to form heterobidentate NHC ligands, allows the synthesis of a range of f-block NHC adducts. The tethering group also allows the lability of the NHC group, and its subsequent reactivity, to be studied. We include a brief survey of the known, structurally characterised f-element–NHC bond distances, and a range of substrates that react to displace the metal-bound NHC group.",
author = "Arnold, {Plly L} and Liddle, {Stephen T}",
year = "2006",
month = "8",
doi = "10.1039/B606829D",
language = "English",
pages = "3959--3971",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "38",

}

RIS

TY - JOUR

T1 - F-block N-heterocyclic carbene complexes

AU - Arnold, Plly L

AU - Liddle, Stephen T

PY - 2006/8

Y1 - 2006/8

N2 - N-Heterocyclic carbenes (NHCs) can bind as two-electron σ-donor ligands to lanthanide and actinide metal cations. In this review we summarise how the incorporation of an anionic group (alkoxide or amido), to form heterobidentate NHC ligands, allows the synthesis of a range of f-block NHC adducts. The tethering group also allows the lability of the NHC group, and its subsequent reactivity, to be studied. We include a brief survey of the known, structurally characterised f-element–NHC bond distances, and a range of substrates that react to displace the metal-bound NHC group.

AB - N-Heterocyclic carbenes (NHCs) can bind as two-electron σ-donor ligands to lanthanide and actinide metal cations. In this review we summarise how the incorporation of an anionic group (alkoxide or amido), to form heterobidentate NHC ligands, allows the synthesis of a range of f-block NHC adducts. The tethering group also allows the lability of the NHC group, and its subsequent reactivity, to be studied. We include a brief survey of the known, structurally characterised f-element–NHC bond distances, and a range of substrates that react to displace the metal-bound NHC group.

U2 - 10.1039/B606829D

DO - 10.1039/B606829D

M3 - Article

SP - 3959

EP - 3971

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 38

ER -