Diboryldiborenes: π‐Conjugated B4 Chains Isoelectronic to the Butadiene DicationCitation formats

  • External authors:
  • Alexander Hermann
  • Jessica Cid
  • James D. Mattock
  • Rian D. Dewhurst
  • Ivo Krummenacher
  • Alfredo Vargas
  • Holger Braunschweig

Standard

Diboryldiborenes: π‐Conjugated B4 Chains Isoelectronic to the Butadiene Dication. / Hermann, Alexander; Cid, Jessica; Mattock, James D. ; Dewhurst, Rian D. ; Krummenacher, Ivo ; Vargas, Alfredo; Ingleson, Michael; Braunschweig, Holger.

In: Angewandte Chemie - International Edition, Vol. 57, No. 32, 06.08.2018.

Research output: Contribution to journalArticle

Harvard

Hermann, A, Cid, J, Mattock, JD, Dewhurst, RD, Krummenacher, I, Vargas, A, Ingleson, M & Braunschweig, H 2018, 'Diboryldiborenes: π‐Conjugated B4 Chains Isoelectronic to the Butadiene Dication', Angewandte Chemie - International Edition, vol. 57, no. 32. https://doi.org/10.1002/anie.201805394

APA

Hermann, A., Cid, J., Mattock, J. D., Dewhurst, R. D., Krummenacher, I., Vargas, A., ... Braunschweig, H. (2018). Diboryldiborenes: π‐Conjugated B4 Chains Isoelectronic to the Butadiene Dication. Angewandte Chemie - International Edition, 57(32). https://doi.org/10.1002/anie.201805394

Vancouver

Hermann A, Cid J, Mattock JD, Dewhurst RD, Krummenacher I, Vargas A et al. Diboryldiborenes: π‐Conjugated B4 Chains Isoelectronic to the Butadiene Dication. Angewandte Chemie - International Edition. 2018 Aug 6;57(32). https://doi.org/10.1002/anie.201805394

Author

Hermann, Alexander ; Cid, Jessica ; Mattock, James D. ; Dewhurst, Rian D. ; Krummenacher, Ivo ; Vargas, Alfredo ; Ingleson, Michael ; Braunschweig, Holger. / Diboryldiborenes: π‐Conjugated B4 Chains Isoelectronic to the Butadiene Dication. In: Angewandte Chemie - International Edition. 2018 ; Vol. 57, No. 32.

Bibtex

@article{2bd403ff49b04bb1973a2da9a4f531f3,
title = "Diboryldiborenes: π‐Conjugated B4 Chains Isoelectronic to the Butadiene Dication",
abstract = "sp2‐sp3 diborane species based on bis(catecholato)diboron and N‐heterocyclic carbenes (NHCs) are subjected to catechol/bromide exchange selectively at the sp3 boron atom. The reduction of the resulting 1,1‐dibromodiborane adducts led to reductive coupling and isolation of doubly NHC‐stabilized 1,2‐diboryldiborenes. These compounds are the first examples of molecules exhibiting π‐electron delocalization over an all‐boron chain.",
author = "Alexander Hermann and Jessica Cid and Mattock, {James D.} and Dewhurst, {Rian D.} and Ivo Krummenacher and Alfredo Vargas and Michael Ingleson and Holger Braunschweig",
year = "2018",
month = "8",
day = "6",
doi = "10.1002/anie.201805394",
language = "English",
volume = "57",
journal = "Angewandte Chemie, International Edition",
issn = "1433-7851",
publisher = "John Wiley & Sons Ltd",
number = "32",

}

RIS

TY - JOUR

T1 - Diboryldiborenes: π‐Conjugated B4 Chains Isoelectronic to the Butadiene Dication

AU - Hermann, Alexander

AU - Cid, Jessica

AU - Mattock, James D.

AU - Dewhurst, Rian D.

AU - Krummenacher, Ivo

AU - Vargas, Alfredo

AU - Ingleson, Michael

AU - Braunschweig, Holger

PY - 2018/8/6

Y1 - 2018/8/6

N2 - sp2‐sp3 diborane species based on bis(catecholato)diboron and N‐heterocyclic carbenes (NHCs) are subjected to catechol/bromide exchange selectively at the sp3 boron atom. The reduction of the resulting 1,1‐dibromodiborane adducts led to reductive coupling and isolation of doubly NHC‐stabilized 1,2‐diboryldiborenes. These compounds are the first examples of molecules exhibiting π‐electron delocalization over an all‐boron chain.

AB - sp2‐sp3 diborane species based on bis(catecholato)diboron and N‐heterocyclic carbenes (NHCs) are subjected to catechol/bromide exchange selectively at the sp3 boron atom. The reduction of the resulting 1,1‐dibromodiborane adducts led to reductive coupling and isolation of doubly NHC‐stabilized 1,2‐diboryldiborenes. These compounds are the first examples of molecules exhibiting π‐electron delocalization over an all‐boron chain.

U2 - 10.1002/anie.201805394

DO - 10.1002/anie.201805394

M3 - Article

VL - 57

JO - Angewandte Chemie, International Edition

JF - Angewandte Chemie, International Edition

SN - 1433-7851

IS - 32

ER -