[CrF(O2CtBu)2]9: Synthesis and Characterization of a Regular Homometallic Ring with an Odd Number of Metal Centers and Electrons

Research output: Contribution to journalArticle

  • External authors:
  • Robert Woolfson
  • Grigore Timco
  • Alessandro Chiesa
  • Inigo Vitorica-Yrezabal
  • Tatiana Guidi
  • Eva Pavarini
  • Paolo Santini
  • Stefano Carretta

Abstract

The first regular homometallic ring containing an
odd number of metal centers is reported. The ring was
synthesized by means of amine-templated self-assembly.
Extensive physical characterization studies, including magnetic
measurements, powder inelastic neutron scattering (INS), and
DFT calculations, show that the molecule has a near perfect
match to the expected behavior for a frustrated system with the
lowest energy pair of S=1/2 spin states separated by only
0.1 meV (0.8 cm¢1).

Bibliographical metadata

Original languageEnglish
Article number8856 –8859
JournalAngewandte Chemie - International Edition
Volume55
Issue number31
Early online date13 Jun 2016
DOIs
StatePublished - 20 Jul 2016