Binding CO2 by a Cr8 metallacrown

Research output: Contribution to journalArticle

  • External authors:
  • Inigo Vitorica-Yrezabal
  • Daniel Sava
  • Grigore Timco
  • Martyn Brown
  • Mathew Savage
  • Harry Godfrey
  • Florian Moreau
  • Lee Brammer
  • Richard Winpenny

Abstract

The {Cr8} metallacrown [CrF(O2CtBu)2]8, containing a F-lined internal cavity, shows high selectivity for CO2 over N2. DFT calculations and absorption studies support the multiple binding of F-groups to the C-center of CO2 (C⋅⋅⋅F 3.190(9)–3.389(9) Å), as confirmed by single-crystal X-ray diffraction.

Bibliographical metadata

Original languageEnglish
JournalAngewandte Chemie - International Edition
Volume56
Issue number20
Early online date13 Apr 2017
DOIs
StatePublished - 2017