Anisotropy barrier enhancement via ligand substitution in tetranuclear \{Co$^{\textrm{{III}}}$$_{\textrm{2}}$Ln$^{\textrm{{III}}}$$_{\textrm{2}}$\} single molecule magnets

Research output: Contribution to journalArticle

Abstract

The replacement of coordinated acetylacetonate for nitrate around a {DyIII} ion results in the enhancement of the single molecule magnet properties of a \{{CoIII}2DyIII2\} complex, resulting in a large thermal energy barrier and reduced quantum tunnelling at low temperatures. The analogous {TbIII} complex displays f

Bibliographical metadata

Original languageEnglish
Pages (from-to)6965-6967
Number of pages3
JournalChemical Communications
Volume49
Issue number62
DOIs
Publication statusPublished - Jul 2013