An all-vanadiuni(III) hexametalate lindqvist structure and its chromium and iron analogues

Research output: Contribution to journalArticle

  • Authors:
  • Luke J. Batchelor
  • Rachel Shaw
  • Sophie J. Markey
  • Madeline Helliwell
  • Eric J L McInnes

Abstract

(Figure Presented) Lindqvist structures: We report the isolation of the all-vanadium(III) analogue (see figure) of the fully reduced (all-vanadium(IV)) hexavanadate structure from formal substitution of the {VIIICl} 2+ and {VIVO}2+ fragments. The chemistry can be extended to the analogous CrIII and FeIII cluster anions. Magnetic data for the series are presented. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

Bibliographical metadata

Original languageEnglish
Pages (from-to)5554-5557
Number of pages3
JournalChemistry - A European Journal
Volume16
Issue number19
DOIs
Publication statusPublished - 17 May 2010

Related information