An Actinide Zintl Cluster: A Tris(triamidouranium)μ3-η2:η2:η2-Heptaphosphanortricyclane and Its Diverse Synthetic UtilityCitation formats

  • External authors:
  • Dipti Patel
  • William Lewis
  • Alexander J. Blake

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An Actinide Zintl Cluster: A Tris(triamidouranium)μ3-η2:η2:η2-Heptaphosphanortricyclane and Its Diverse Synthetic Utility. / Patel, Dipti; Tuna, Floriana; McInnes, Eric J L; Lewis, William; Blake, Alexander J.; Liddle, Stephen T.

In: Angewandte Chemie (International Edition), Vol. 52, No. 50, 09.12.2013, p. 13334-13337.

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Patel, Dipti ; Tuna, Floriana ; McInnes, Eric J L ; Lewis, William ; Blake, Alexander J. ; Liddle, Stephen T. / An Actinide Zintl Cluster: A Tris(triamidouranium)μ3-η2:η2:η2-Heptaphosphanortricyclane and Its Diverse Synthetic Utility. In: Angewandte Chemie (International Edition). 2013 ; Vol. 52, No. 50. pp. 13334-13337.

Bibtex

@article{53b3cf49ecc54f26b1dc1074e8539955,
title = "An Actinide Zintl Cluster: A Tris(triamidouranium)μ3-η2:η2:η2-Heptaphosphanortricyclane and Its Diverse Synthetic Utility",
abstract = "A diuranium(V) arene complex reductively cleaves P4 to give a triuranium heptaphosphanortricyclane cluster (see picture; Ugreen, Ppurple, Nblue, Siorange). This cluster is the first example of a molecular actinide [P7] Zintl complex and the first example of uranium-promoted catenation of P4. This complex undergoes a wide range of reactions under mild conditions to afford liberated P7R3 phosphanortricyclanes. {\circledC} 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.",
keywords = "actinides, reduction, uranium, white phosphorus, Zintl phases",
author = "Dipti Patel and Floriana Tuna and McInnes, {Eric J L} and William Lewis and Blake, {Alexander J.} and Liddle, {Stephen T.}",
note = "Times Cited: 2",
year = "2013",
month = "12",
day = "9",
doi = "10.1002/anie.201306492",
language = "English",
volume = "52",
pages = "13334--13337",
journal = "Angewandte Chemie, International Edition",
issn = "1433-7851",
publisher = "John Wiley & Sons Ltd",
number = "50",

}

RIS

TY - JOUR

T1 - An Actinide Zintl Cluster: A Tris(triamidouranium)μ3-η2:η2:η2-Heptaphosphanortricyclane and Its Diverse Synthetic Utility

AU - Patel, Dipti

AU - Tuna, Floriana

AU - McInnes, Eric J L

AU - Lewis, William

AU - Blake, Alexander J.

AU - Liddle, Stephen T.

N1 - Times Cited: 2

PY - 2013/12/9

Y1 - 2013/12/9

N2 - A diuranium(V) arene complex reductively cleaves P4 to give a triuranium heptaphosphanortricyclane cluster (see picture; Ugreen, Ppurple, Nblue, Siorange). This cluster is the first example of a molecular actinide [P7] Zintl complex and the first example of uranium-promoted catenation of P4. This complex undergoes a wide range of reactions under mild conditions to afford liberated P7R3 phosphanortricyclanes. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - A diuranium(V) arene complex reductively cleaves P4 to give a triuranium heptaphosphanortricyclane cluster (see picture; Ugreen, Ppurple, Nblue, Siorange). This cluster is the first example of a molecular actinide [P7] Zintl complex and the first example of uranium-promoted catenation of P4. This complex undergoes a wide range of reactions under mild conditions to afford liberated P7R3 phosphanortricyclanes. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - actinides

KW - reduction

KW - uranium

KW - white phosphorus

KW - Zintl phases

U2 - 10.1002/anie.201306492

DO - 10.1002/anie.201306492

M3 - Article

VL - 52

SP - 13334

EP - 13337

JO - Angewandte Chemie, International Edition

JF - Angewandte Chemie, International Edition

SN - 1433-7851

IS - 50

ER -