A Molecular Trefoil Knot From a Trimeric Circular Helicate

Research output: Contribution to journalArticle

  • External authors:
  • Liang Zhang
  • David August
  • Jiankang Zhong
  • George Whitehead
  • Inigo Vitorica-Yrezabal

Abstract

We report the two-step synthesis of a molecular trefoil knot in 90 % overall yield through the self-assembly of a twelve-component trimeric circular zinc helicate followed by ring closing metathesis of six pendant alkene chains. Both the trimeric circular helicate intermediate and the resulting trefoil knot were characterized by NMR spectroscopy, mass spectrometry and X-ray crystallography.

Bibliographical metadata

Original languageEnglish
JournalAmerican Chemical Society. Journal
Early online date14 Mar 2018
DOIs
Publication statusPublished - 2018

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