Organic Chemistry Group

Publications

  1. 2013
  2. Published

    Arene-metal p-complexation as a traceless reactivity enhancer for C-H arylation

    Ricci, P., Kr?mer, K., Cambeiro, X. C. & Larrosa, I., 2013, In : Journal of the American Chemical Society. 135, 36, p. 13258-13261 4 p.

    Research output: Contribution to journalArticle

  3. Published

    Direct ortho-arylation of ortho-substituted benzoic acids: Overriding Pd-catalyzed protodecarboxylation

    Arroniz, C., Ironmonger, A., Rassias, G. & Larrosa, I., 2013, In : Organic Letters. 15, 4, p. 910-913 4 p.

    Research output: Contribution to journalArticle

  4. Published

    Metalation dictates remote regioselectivity: Ruthenium-catalyzed functionalization of meta CAr-H bonds

    Julia-Hernandez, F., Simonetti, M. & Larrosa, I., 2013, In : Angewandte Chemie - International Edition. 52, 44, p. 11458-11460 3 p.

    Research output: Contribution to journalArticle

  5. Published

    On water phosphine-free palladium-catalyzed room temperature C-H arylation of indoles

    Islam, S. & Larrosa, I., 2013, In : Chemistry - A European Journal. 19, 45, p. 15093-15096 4 p.

    Research output: Contribution to journalArticle

  6. Published

    Redox-controlled selectivity of C-H activation in the oxidative cross-coupling of arenes

    Cambeiro, X. C., Boorman, T. C., Lu, P. & Larrosa, I., 2013, In : Angewandte Chemie - International Edition. 52, 6, p. 1781-1784 4 p.

    Research output: Contribution to journalArticle

  7. Published

    The interplay of thermodynamics and kinetics in dictating organocatalytic reactivity and selectivity

    Burés, J., Armstrong, A. & Blackmond, D. G., 2013, In : Pure and Applied Chemistry. 85

    Research output: Contribution to journalArticle

  8. 2012
  9. Published

    On the origin of oxygen isotope exchange induced ferroelectricity in strontium titanate

    Deng, H-Y., Lam, C-H. & Huang, H. T., 3 Jul 2012, In : European Physical Journal B. 85, p. 234-239 6 p.

    Research output: Contribution to journalArticle

  10. Published

    Curtin–Hammett Paradigm for Stereocontrol in Organocatalysis by Diarylprolinol Ether Catalysts

    Burés, J., Armstrong, A. & Blackmond, D. G., 2012, In : Journal of the American Chemical Society. 134, p. 6741-6750 10 p.

    Research output: Contribution to journalArticle

  11. Published

    Decarboxylative carbon-carbon bond-forming transformations of (hetero)aromatic carboxylic acids

    Cornella, J. & Larrosa, I., 2012, In : Synthesis. 44, 5, p. 653-676 24 p.

    Research output: Contribution to journalReview article

  12. Published

    Kinetic correlation between aldehyde/enamine stereoisomers in reactions between aldehydes with [small alpha]-stereocenters and chiral pyrrolidine-based catalysts

    Bures, J., Armstrong, A. & Blackmond, D. G., 2012, In : Chemical Science. 3, p. 1273-1277 5 p.

    Research output: Contribution to journalArticle

  13. Published

    Recent Advances in the C2 and C3 Regioselective Direct Arylation of Indoles

    Lebrasseur, N. & Larrosa, I., 2012, In : Advances in Heterocyclic Chemistry. 105, p. 309-351 43 p.

    Research output: Contribution to journalArticle

  14. Published

    Relative Tendency of Carbonyl Compounds To Form Enamines

    Sánchez, D., Bastida, D., Burés, J., Isart, C., Pineda, O. & Vilarrasa, J., 2012, In : Organic Letters. 14, p. 536-539 4 p.

    Research output: Contribution to journalArticle

  15. Published

    Selective deuteration of (hetero)aromatic compounds via deutero-decarboxylation of carboxylic acids

    Grainger, R., Nikmal, A., Cornella, J. & Larrosa, I., 2012, In : Organic and Biomolecular Chemistry. 10, 16, p. 3172-3174 3 p.

    Research output: Contribution to journalArticle

  16. Published

    Studies on the total synthesis of lactonamycin: Synthesis of the fused pentacyclic B-F ring unit

    Jacques, S. A., Michaelis, S., Gebhardt, B., Blum, A., Lebrasseur, N., Larrosa, I., White, AJP. & Barrett, AGM., 2012, In : European Journal of Organic Chemistry. 1, p. 107-113 7 p.

    Research output: Contribution to journalArticle

  17. 2011
  18. Published

    Gold-mediated C-H bond functionalisation

    Boorman, T. C. & Larrosa, I., Apr 2011, In : Chemical Society Reviews. 40, 4, p. 1910-1925 16 p.

    Research output: Contribution to journalReview article

  19. Published

    A novel mode of reactivity for gold(I): The decarboxylative activation of (hetero)aromatic carboxylic acids

    Cornella, J., Rosillo-Lopez, M. & Larrosa, I., 2011, In : Advanced synthesis & catalysis. 353, 8, p. 1359-1366 8 p.

    Research output: Contribution to journalArticle

  20. Published

    Carboxylic acids as traceless directing groups for formal meta-selective direct arylation

    Cornella, J., Righi, M. & Larrosa, I., 2011, In : Angewandte Chemie - International Edition. 50, 40, p. 9429-9432 4 p.

    Research output: Contribution to journalArticle

  21. Published

    Enamine Carboxylates as Stereodetermining Intermediates in Prolinate Catalysis

    Hein, J. E., Burés, J., Lam, Y., Hughes, M., Houk, K. N., Armstrong, A. & Blackmond, D. G., 2011, In : Organic Letters. 13, p. 5644-5647 4 p.

    Research output: Contribution to journalArticle

  22. Published

    Gold(III) Complexes Catalyze Deoximations/Transoximations at Neutral pH

    Isart, C., Bastida, D., Burés, J. & Vilarrasa, J., 2011, In : Angewandte Chemie International Edition. 50, p. 3275-3279 5 p.

    Research output: Contribution to journalArticle

  23. Published

    Mechanistic rationalization of organocatalyzed conjugate addition of linear aldehydes to nitro-olefins

    Bures, J., Armstrong, A. & Blackmond, D. G., 2011, In : J Am Chem Soc. 133, p. 8822-8825 4 p.

    Research output: Contribution to journalArticle

  24. Published

    Recent Advances in the C-2 Regioselective Direct Arylation of Indoles

    Boorman, T. C. & Larrosa, I., 2011, Progress in Heterocyclic Chemistry. Vol. 22. p. 1-20 20 p.

    Research output: Chapter in Book/Report/Conference proceedingChapter

  25. Published

    Two flavors of PEPPSI-IPr: Activation and diffusion control in a single NHC-ligated Pd catalyst?

    Larrosa, I., Somoza, C., Banquy, A. & Goldup, S. M., 2011, In : Organic Letters. 13, 1, p. 146-149 4 p.

    Research output: Contribution to journalArticle

  26. 2010
  27. Published

    Decarboxylative homocoupling of (hetero)aromatic carboxylic acids

    Cornella, J., Lahlali, H. & Larrosa, I., 2010, In : Chemical Communications. 46, 43, p. 8276-8278 3 p.

    Research output: Contribution to journalArticle

  28. Published

    Gold(I)-mediated C-H activation of arenes

    Lu, P., Boorman, T. C., Slawin, AMZ. & Larrosa, I., 2010, In : Journal of the American Chemical Society. 132, 16, p. 5580-5581 2 p.

    Research output: Contribution to journalArticle

  29. Published

    Reaction of Dess-Martin periodinane with 2-(alkylselenyl)pyridines. Dehydration of primary alcohols under extraordinarily mild conditions: Tetrahedron Letters

    Andreou, T., Bures, J. & Vilarrasa, J., 2010, In : Tetrahedron Letters. 51, p. 1863-1866 4 p.

    Research output: Contribution to journalArticle

  30. 2009
  31. Published

    AuBr3-Catalyzed Thiooxime-to-Carbonyl Conversion: From Chiral Aliphatic Nitro Compounds to Ketones without Racemization

    Bures, J., Isart, C. & Vilarrasa, J., 2009, In : Organic Letters. 11, p. 4414-4417 4 p.

    Research output: Contribution to journalArticle

  32. Published

    Catalytic Staudinger-Vilarrasa Reaction for the Direct Ligation of Carboxylic Acids and Azides: Journal of Organic Chemistry

    Bures, J., Martin, M., Urpi, F. & Vilarrasa, J., 2009, In : The Journal of organic chemistry. 74, p. 2203-2206 4 p.

    Research output: Contribution to journalArticle

  33. Published

    Intermodular decarboxylative direct C-3 arylation of indoles with benzoic acids

    Cornelia, J., Lu, P. & Larrosa, I., 2009, In : Organic Letters. 11, 23, p. 5506-5509 4 p.

    Research output: Contribution to journalArticle

  34. Published

    Silver-catalysed protodecarboxylation of ortho-substituted benzoic acids

    Cornella, J., Sanchez, C., Banawa, D. & Larrosa, I., 2009, In : Chemical Communications. 46, p. 7176-7178 3 p.

    Research output: Contribution to journalArticle

  35. Published

    Silver-catalyzed protodecarboxylation of heteroaromatic carboxylic acids

    Lu, P., Sanchez, C., Cornella, J. & Larrosa, I., 2009, In : Organic Letters. 11, 24, p. 5710-5713 4 p.

    Research output: Contribution to journalArticle

  36. Published

    Stereoselective synthesis of a- And ?-C-glycosides by addition of titanium enolates to glycals

    Galvez, E., Larrosa, I., Romea, P. & Urpi, F., 2009, In : SYNLETT. 18, p. 2982-2986 5 p.

    Research output: Contribution to journalArticle

  37. 2008
  38. Published

    Synthesis of six-membered oxygenated heterocycles through carbon-oxygen bond-forming reactions

    Larrosa, I., Romea, P. & Urpí, F., 17 Mar 2008, In : Tetrahedron. 64, 12, p. 2683-2723 41 p.

    Research output: Contribution to journalReview article

  39. Published

    Catalytic, PMe3-mediated conversion of secondary nitroalkanes to ketones: a very mild Nef-type process

    Burés, J. & Vilarrasa, J., 2008, In : Tetrahedron Letters. 49, p. 441-444 4 p.

    Research output: Contribution to journalArticle

  40. Published

    Room temperature and phosphine free palladium catalyzed direct C-2 arylation of indoles

    Lebrasseur, N. & Larrosa, I., 2008, In : Journal of the American Chemical Society. 130, 10, p. 2926-2927 2 p.

    Research output: Contribution to journalArticle

  41. Published

    Seebach's oxazolidinone is a good catalyst for aldol reactions: Tetrahedron Lett.

    Isart, C., Bures, J. & Vilarrasa, J., 2008, In : Tetrahedron Letters. 49, p. 5414-5418 5 p.

    Research output: Contribution to journalArticle

  42. 2007
  43. Published

    Efficient Preparation of N-Phenylsulfenyl Ketimines from Oximes or Nitro Compounds without Racemization of α-Stereocenters

    Burés, J., Isart, C. & Vilarrasa, J., 2007, In : Organic Letters. 9, p. 4635-4638 4 p.

    Research output: Contribution to journalArticle

  44. 2006
  45. Published

    Highly convergent three component benzyne coupling: The total synthesis of ent-clavilactone B

    Larrosa, I., Da Silva, M. I., G??mez, P. M., Hannen, P., Ko, E., Lenger, S. R., Linke, S. R., White, AJP., Wilton, D. & Barrett, AGM., 2006, In : Journal of the American Chemical Society. 128, 43, p. 14042-14043 2 p.

    Research output: Contribution to journalArticle

  46. Published

    Stereoselective synthesis of the western hemisphere of salinomycin

    Larrosa, I., Romea, P. & Urpi, F., 2006, In : Organic Letters. 8, 3, p. 527-530 4 p.

    Research output: Contribution to journalArticle

  47. 2005
  48. Published

    Bismuth-catalyzed benzylic oxidations with tert-butyl hydroperoxide

    Bonvin, Y., Callens, E., Larrosa, I., Henderson, D. A., Oldham, J., Burton, A. J. & Barrett, AGM., 2005, In : Organic Letters. 7, 21, p. 4549-4552 4 p.

    Research output: Contribution to journalArticle

  49. 2004
  50. Published

    Mild cleavage of aryl mesylates: Methanesulfonate as potent protecting group for phenols

    Ritter, T., Stanek, K., Larrosa, I. & Carreira, E. M., 2004, In : Organic Letters. 6, 9, p. 1513-1514 2 p.

    Research output: Contribution to journalArticle

  51. 2003
  52. Published

    Studies on the intramolecular C-H?X (X = O, S) interactions in (S)-N-acyl-4-isopropyl-1,3-thiazolidine-2-thiones and related 1,3-oxazolidin-2-ones

    Cosp, A., Larrosa, I., Anglada, J. M., Bofill, J. M., Romea, P. & Urpi, F., 2003, In : Organic Letters. 5, 16, p. 2809-2812 4 p.

    Research output: Contribution to journalArticle

  53. Published

    Synthesis of O-benzyl protected anti aldols through the cross-coupling reaction of dibenzyl acetals with a chiral titanium enolate

    Cosp, A., Larrosa, I., Vilas??s, I., Romea, P., Urp??, F. & Vilarrasa, J., 2003, In : SYNLETT. 8, p. 1109-1112 4 p.

    Research output: Contribution to journalArticle

  54. 2002
  55. Published

    Unprecedented Highly Stereoselective a- and ??-C-Glycosidation with Chiral Titanium Enolates

    Larrosa, I., Romea, P., Urp??, F., Balsells, D., Vilarrasa, J., Font-Bardia, M. & Solans, X., 2002, In : Organic Letters. 4, 26, p. 4651-4654 4 p.

    Research output: Contribution to journalArticle

  56. 2001
  57. Published

    The abnormal cytotoxicities of 2,5-diaziridinyl-1,4-benzoquinone-3-phenyl esters.

    Francesco, D., Angela, M., Hargreaves, R. H. J., Wallace, T., Mayalarp, S. P., Hazrati, A., Hartley, J. A. & Butler, J., 2001, In : Anti-Cancer Drug Design. 15, 5, p. 347-359 12 p.

    Research output: Contribution to journalArticle

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